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| 基于Willgerodt-Kindler反应的两种二茂铁羧酸的合成及机理研究 | |
| 引用本文： | 邱潇,张久峰,赵红莉,蓝闽波.基于Willgerodt-Kindler反应的两种二茂铁羧酸的合成及机理研究[J].有机化学,2009,29(5):748-752. |
| 作者姓名： | 邱潇 张久峰 赵红莉 蓝闽波 |
| 作者单位： | 1. 华东理工大学结构可控先进功能材料及其制备教育部重点实验室,上海,200237 2. 华东理工大学结构可控先进功能材料及其制备教育部重点实验室,上海,200237;华东理工大学分析测试中心,上海,200237 |
| 基金项目： | Chemistries and Apparatus for Nanobiotechnology(NACBO)，欧盟第六框架项目，科技部国际合作项目，上海市纳米专项项目 |
| 摘 要： | 以Na2S•9H2O为催化剂, 通过Willgerodt-Kindler反应分别合成了二茂铁乙酸和1,1’-二茂铁二乙酸, 用IR, 1H NMR, MS和元素分析对产物分别进行了结构表征, 并利用GC-MS研究了该反应机理, 推测反应是由多硫阴离子进攻羰基α碳所引发, 同时讨论了影响反应的各种因素. |
| 关 键 词： | 二茂铁乙酸 1 1’-二茂铁二乙酸 Willgerodt-Kindler反应 合成 机理 |
| 收稿时间： | 2008-8-8 |
| 修稿时间： | 2008-11-17 |
Synthesis of Two Ferrocene Carboxylic Acids via Willgerodt-Kindler Reaction and Mechanism |
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| Qiu,Xiao,Zhang,Jiufeng,Zhao,Hongli,Lan,Minbo.Synthesis of Two Ferrocene Carboxylic Acids via Willgerodt-Kindler Reaction and Mechanism[J].Chinese Journal of Organic Chemistry,2009,29(5):748-752. | |
| Authors: | Qiu Xiao Zhang Jiufeng Zhao Hongli Lan Minbo |
| Institution: | (a Key Laboratory of Advanced Materials (ECUST), Ministry of Education, East China University of Science and Technology, Shanghai 200237) (b Research Center of Analysis and Test, East China University of Science and Technology, Shanghai 200237) |
| Abstract: | Ferrocenylacetic acid and 1,1’-ferrocenyldiacetic acid were synthesized via Willgerodt-Kindler reaction in the presence of Na2S•9H2O as catalyst. Their structures were characterized by IR, 1H NMR, MS techniques and elemental analysis. By GC-MS, the mechanism was proposed that the reaction was initiated by the polysulfide anion attacking at the α-carbon. Further factors affecting the reaction were also discussed. |
| Keywords: | ferrocenylacetic acid 1 l’-ferrocenyldiacetic acid Willgerodt-Kindler reaction systhesis mechani |
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