| 新型含短氟碳链侧基的氧杂环丁烷单体的合成与表征 |
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| 引用本文： | 王君,黄继庆,黄焰根,卿凤翎. 新型含短氟碳链侧基的氧杂环丁烷单体的合成与表征[J]. 有机化学, 2009, 29(12): 1969-1974 |
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| 作者姓名： | 王君 黄继庆 黄焰根 卿凤翎 |
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| 作者单位： | 1. 东华大学化学化工与生物工程学院,上海,201620
2. 东华大学化学化工与生物工程学院,上海,201620;中国科学院上海有机化学研究所有机氟化学重点实验室,上海,200032 |
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| 摘 要： | 应用含短氟碳链的功能性聚合物可以避免因使用含长氟碳链化合物给环境带来的潜在危害. 以全氟丁基磺酰氟为原料, 通过磺酰化和N-烷基化合成带有端羟基的中间体4, 再通过2,2-二溴甲基氧杂环丁烷(2)与4的Williamson醚化反应合成了含全氟丁基磺酰胺侧基的新型氧杂环丁烷衍生物1a和1b. 以5,5-二甲基海因为原料, 采用类似的合成路线, 合成了带海因侧基的新型氧杂环丁烷单体6.
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| 关 键 词： | 氧杂环丁烷 全氟丁基磺酰胺 海因 合成 表征 |
| 收稿时间： | 2009-04-09 |
| 修稿时间： | 2009-06-04 |
Synthesis and Characterization of Novel Oxetane Monomers Containing Short Perfluorocarbon Side Chains |
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| Wang,Jun,Huang,Jiqing,Huang,Yangen,Qing,Fengling. Synthesis and Characterization of Novel Oxetane Monomers Containing Short Perfluorocarbon Side Chains[J]. Chinese Journal of Organic Chemistry, 2009, 29(12): 1969-1974 |
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| Authors: | Wang Jun Huang Jiqing Huang Yangen Qing Fengling |
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| Affiliation: | (College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620)( Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032) |
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| Abstract: | The application of functional polymers containing short perfluorinated side chains could avoid the potential environmental damage caused by the use of compounds containing long perfluorinated side chains. Starting from perfluorobutyl sulfuryl fluoride, intermediate 4 with a hydroxy end group was obtained by sulfonylation and N-alkylation, then novel oxetane derivatives 1a and 1b with a nonafluorobu-tane-1-sulfonamide side chain were synthesized via Williamson etherification between 4 and 2,2-di(bromomethyl)oxetane (2). Similar procedure was applied to the preparation of hydantoin-oxetane monomer 6 using 5,5-dimethylhydantoin as starting material. |
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| Keywords: | oxetane perfluorobutylated sulfonamide hydantoin synthesis characterization |
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