| 镍催化芳基-芳基交叉偶联反应的配体研究新进展 |
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| 引用本文： | 李永清,曹育才,叶晓峰,周慧.镍催化芳基-芳基交叉偶联反应的配体研究新进展[J].有机化学,2011,31(10). |
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| 作者姓名： | 李永清 曹育才 叶晓峰 周慧 |
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| 作者单位： | 上海化工研究院 上海200062 |
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| 基金项目： | 上海市科委国际科技合作基金 |
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| 摘 要： | 联芳基结构在天然产物、药物以及各种光电材料中广泛存在,自20世纪70年代以来,各种过渡金属催化的芳基-芳基偶联手段得到普遍应用,配体、底物、辅助手段等的研究也快速发展.从配体类型的角度综述了镍催化的芳基-芳基交叉偶联反应.
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| 关 键 词： | 镍 过渡金属催化 配体 联芳烃 交叉偶联 |
New Progress in Nickel-Catalyzed Aryl-Aryl Cross-Coupling Reactions: A Ligand Survey |
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| Li Yongqing,Cao Yucai,Ye Xiaofeng,Zhou Hui.New Progress in Nickel-Catalyzed Aryl-Aryl Cross-Coupling Reactions: A Ligand Survey[J].Chinese Journal of Organic Chemistry,2011,31(10). |
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| Authors: | Li Yongqing Cao Yucai Ye Xiaofeng Zhou Hui |
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| Institution: | Li,Yongqing Cao,Yucai Ye,Xiaofeng Zhou,Hui(Shanghai Research Institute of Chemical Industry,Shanghai 200062) |
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| Abstract: | Biaryls widely exist in natural products,pharmaceuticals and various photoelectricity materials.Remarkable progress of cross-couplings has been achieved since the 70s of 20th century using a few transi-tion metals for the production of biaryls.Particular attentions are being focused on ligands,substrates and assistant techniques.Nickel-catalyzed aryl-aryl cross-coupling reactions are reviewed from the point of ligands. |
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| Keywords: | nickel transition metal catalysis ligand biaryl cross coupling |
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