| 四硫富瓦烯和联萘基构建的新型多功能氧化还原荧光开关 |
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| 引用本文： | 王永秋,迟兴宝.四硫富瓦烯和联萘基构建的新型多功能氧化还原荧光开关[J].有机化学,2006,26(11):1533-1538. |
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| 作者姓名： | 王永秋 迟兴宝 |
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| 作者单位： | 淮北煤炭师范学院化学系,淮北,235000 |
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| 基金项目： | 安徽省教育厅青年教师资助项目． |
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| 摘 要： | 利用3-溴甲基-2,2'-二甲氧基亚甲氧基-1,1'-联萘和四硫富瓦烯四硫盐反应合成新的联萘基四硫富瓦烯衍生物, 通过电化学氧化还原法发现其荧光能够可逆地增强和减弱, 因此它是一个新的氧化还原荧光开关. 并通过循环伏安法发现这种氧化还原荧光开关可以选择性地识别和跟踪Fe3＋.
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| 关 键 词： | 氧化还原荧光开光 四硫富瓦烯 联萘基 循环伏安 |
| 收稿时间： | 12 22 2005 12:00AM |
| 修稿时间： | 05 9 2006 12:00AM |
A New Multifunctional Redox-Fluorescence Switch Based onTetrathiafulvalene and Binaphthyl Units |
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| WANG,Yong-Qiu,CHI,Xing-Bao.A New Multifunctional Redox-Fluorescence Switch Based onTetrathiafulvalene and Binaphthyl Units[J].Chinese Journal of Organic Chemistry,2006,26(11):1533-1538. |
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| Authors: | WANG Yong-Qiu CHI Xing-Bao |
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| Institution: | Department of Chemistry, Huaibei Coal Industry Teachers College, Huaibei 235000 |
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| Abstract: | A new redox fluorescence switch based on tetrathiafulvalene and binaphthyl units was synthesized by 3-bromomethyl-2,2'-bis(methoxymethyloxy)-1,1'-binaphthalene and tetrathiafulvalene tetra-thiolates. Its fluorescence can be reversibly modulated by sequential electrochemical oxidation and reduction. So it is a new redox fluorescence switch. It may selectively recognize and detect Fe3 by cyclic voltammetry. |
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| Keywords: | redox fluorescence switch tetrathiaflvalene binaphthyl cyclic voltammetry |
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