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| 氮-二供电子链取代邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应 | |
| 引用本文： | 金英学,谭广慧,王天赤,魏树权,王进军.氮-二供电子链取代邻苯二甲酰亚胺衍生物的光诱导单电子转移环化反应[J].有机化学,2010,30(4):595-600. |
| 作者姓名： | 金英学 谭广慧 王天赤 魏树权 王进军 |
| 作者单位： | 1. 哈尔滨师范大学化学化工学院,哈尔滨,150025 2. 烟台大学化学生物理工学院,烟台,264005 |
| 基金项目： | 国家自然科学基金，黑龙江省教育厅海外学人科研基金，国家人事部留学人员科技活动项目择优资助，教育部留学回国人员科研启动基金，山东省自然科学基金 |
| 摘 要： | 含有较短硫醚链和较长聚乙氧基醚链的邻苯二甲酰亚胺衍生物在甲醇溶剂中发生光诱导单电子转移环化反应(SET),以很高的反应区域选择性和很高的产率得到由较短的硫醚链参与构成的环状化合物.所有新化合物均经NMR和EI-MS确定其结构. |
| 关 键 词： | 二供电子链 邻苯二甲酰亚胺 单电子转移 环化反应 |
| 收稿时间： | 2009-05-27 |
| 修稿时间： | 2009-08-10 |
Photoinduced Cyclization Reactions of Phthalimide Derivatives /V-Linked Two Electrondonating Chains by Single Electron Transfer |
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| Jin Yingxue,Tan Guanghui,Wang Tianchi,Wei Shuquan,Wang Jinjun.Photoinduced Cyclization Reactions of Phthalimide Derivatives /V-Linked Two Electrondonating Chains by Single Electron Transfer[J].Chinese Journal of Organic Chemistry,2010,30(4):595-600. | |
| Authors: | Jin Yingxue Tan Guanghui Wang Tianchi Wei Shuquan Wang Jinjun |
| Institution: | (College of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025) (Science and Engineering College of Chemistry and Biology, Yantai University, Yantai 264005) |
| Abstract: | Phthalimide derivatives containing a shorter thioether chain and a longer poly-ethylenoxy chain could undergo a photoinduced single electron transfer cyclization reaction in methanol solvent to provide cylic compounds that were constituted with the shorter thioether chain in high regioselectivity and high yield. The structures of all new compounds were confirmed by NMR and EI-MS data. |
| Keywords: | electrondonating bis-chain phthalimide single electron transfer cyclization reaction |
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