| 含硫—硫键的新型苯胺类化合物的合成 |
| |
| 引用本文： | 邓仕任,胡高强,鄢勇,郭建平,黄伟国,周运鸿,李早英.含硫—硫键的新型苯胺类化合物的合成[J].有机化学,2005,25(7):815-819. |
| |
| 作者姓名： | 邓仕任 胡高强 鄢勇 郭建平 黄伟国 周运鸿 李早英 |
| |
| 作者单位： | 1. 武汉大学化学与分子科学学院,武汉,430072
2. 香港浸会大学化学系,香港,九龙塘 |
| |
| 摘 要： | 通过一条新的合成路线得到了一个已知化合物5-氨基-1,4-二氢苯唑并d]-1',2'-二硫因(1). 同时成功地合成了一个新的类似化合物9-氨基-1,2,3,4,5,6,7,8-八氢-2,3,6,7-四硫代蒽(2). 目标化合物及其中间体的结构经1H, 13C NMR, MS, IR确证, X单晶衍射测定了化合物9-硝基-1,2,3,4,5,6,7,8-八氢-2,3,6,7-四硫代蒽(10)的结构.
|
| 关 键 词： | 二硫化合物 苯胺 单晶分析 |
| 收稿时间： | 2004-10-19 |
| 修稿时间： | 2005-2-17 |
A New Synthetic Route of Disulfide Containing Aniline Compounds |
| |
| Deng Shi-ren,HU Gao-qiang,YAN Yong,GUO Jian-Ping,HUANG Wei-guo,ZHOU Yun-hong,Li Zao-ying.A New Synthetic Route of Disulfide Containing Aniline Compounds[J].Chinese Journal of Organic Chemistry,2005,25(7):815-819. |
| |
| Authors: | Deng Shi-ren HU Gao-qiang YAN Yong GUO Jian-Ping HUANG Wei-guo ZHOU Yun-hong Li Zao-ying |
| |
| Institution: | ( College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072)( Department of Chemistry, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong) |
| |
| Abstract: | A new route was employed to synthesize a known compound, 5-amino-1,4-dihydro- benzod]-1',2'-dithiadiene (1), and a new analogue, 9-amino-1,2,3,4,5,6,7,8-octahydro-2,3,6,7-tetrathianthra- cene (2) was successfully synthesized following this method. The structures of target compounds and their intermediates have been characterized by 1H, 13C NMR, MS spectra and the structure of 9-nitro- 1,2,3,4,5,6,7,8-octahydro-2,3,6,7-tetrathianthracene (10) was determined by X-ray single crystal analysis. |
| |
| Keywords: | disulfide aniline single crystal analysis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
|
