| 钯催化烯烃不对称羰基化反应的研究进展 |
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| 引用本文： | 夏九云,杨定乔,龙玉华.钯催化烯烃不对称羰基化反应的研究进展[J].有机化学,2011,31(5). |
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| 作者姓名： | 夏九云 杨定乔 龙玉华 |
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| 作者单位： | 华南师范大学化学与环境学院,广州,510006 |
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| 基金项目： | 国家自然科学基金，广东省自然科学基金 |
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| 摘 要： | 钯催化烯烃不对称羰基化反应是一种合成手性羰基化合物的有效方法之一,综述了近年来钯催化烯烃不对称羰基化反应的最新研究进展,重点讨论了配体、催化体系、反应条件等因素对烯烃羰基化反应的影响,并对烯烃不对称羰基化反应的区域选择性和对映选择性以及可能的反应机理进行了探讨.
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| 关 键 词： | 钯催化 烯烃不对称羰基化 研究进展 |
Progress in Palladium-Catalyzed Asymmetric Carbonylation of Alkenes |
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| Xia Jiuyun,Yang Dingqiao,Long Yuhua.Progress in Palladium-Catalyzed Asymmetric Carbonylation of Alkenes[J].Chinese Journal of Organic Chemistry,2011,31(5). |
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| Authors: | Xia Jiuyun Yang Dingqiao Long Yuhua |
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| Institution: | Xia,Jiuyun Yang,Dingqiao* Long,Yuhua (School of Chemistry and Environment,South China Normal University,Guangzhou 510006) |
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| Abstract: | Palladium-catalyzed asymmetric carbonylation of olefins is one of effective methods for pre-paring chiral carbonyl compounds.The recent advances in palladium-catalyzed asymmetric carbonylation of olefins are reviewed.Great attention was paid to the influences on this kind of carbonylation,ligands,cata-lytic systems,reaction conditions,and so on.What is more,the enantioselectivity,regioselectivity and pos-sible mechanisms are also dicussed in this review. |
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| Keywords: | palladium catalyzed olefin asymmetric carbonylation recent progress |
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