| 基于2(5H)-呋喃酮的碳-杂成键反应研究进展 |
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| 引用本文： | 谭越河,李建晓,洪文坤,汪朝阳.基于2(5H)-呋喃酮的碳-杂成键反应研究进展[J].有机化学,2011,31(5). |
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| 作者姓名： | 谭越河 李建晓 洪文坤 汪朝阳 |
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| 作者单位： | 华南师范大学化学与环境学院,广州,510006 |
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| 基金项目： | 国家自然科学基金，广东省自然科学基金 |
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| 摘 要： | 2(5H)-呋喃酮结构单元广泛存在于天然产物中,同时许多2(5H)-呋喃酮类化合物也是重要的有机合成中间体.因此,基于常见2(5H)-呋喃酮(1)的有机合成研究近年来引起了人们的关注.根据在有机合成反应中成键方式的不同,综述了在2(5H)-呋喃酮(1)环上形成C-O,C-N,C-S,C-P,C-Se,C-Si等碳-杂键的反应研究进展.
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| 关 键 词： | 2(5H)-呋喃酮 碳-杂键 Michael加成 手性 串联反应 |
Progress in the Formation of Carbon-Hetero Bond Based on 2(5H)-Furanones |
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| Tan Yuehe,Li Jianxiao,Hong Wenkun,Wang Zhaoyang.Progress in the Formation of Carbon-Hetero Bond Based on 2(5H)-Furanones[J].Chinese Journal of Organic Chemistry,2011,31(5). |
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| Authors: | Tan Yuehe Li Jianxiao Hong Wenkun Wang Zhaoyang |
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| Institution: | Tan,Yuehe Li,Jianxiao Hong,Wenkun Wang,Zhaoyang*(School of Chemistry and Environment,South China Normal University,Guangzhou 510006) |
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| Abstract: | Recently,the organic synthesis based on 2(5H)-furanones(1) has attracted much attention owing to the unique carbon skeleton of 2(5H)-furanone which is widely present in a variety of natural products and their utility as valuable synthetic intermediates.Classified as different bond kinds,the progress in the forma-tion reactions of carbon-oxygen bond,carbon-nitrogen bond,carbon-sulfur bond,carbon-phosphorus bond,carbon-selenium bond and carbon-silicon bond on 2(5H)-furanone ring is reviewed. |
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| Keywords: | 2(5H)-furanone carbon-hetero bond Michael addition chirality tandem reaction |
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