|
|||||
|
|
| 离子对型[O,N,N]三齿席夫碱镱氯化物的合成及其晶体结构 | |
| 引用本文： | 李邦玉,喻龙宝,王耀荣,姚英明,张勇,沈琪.离子对型[O,N,N]三齿席夫碱镱氯化物的合成及其晶体结构[J].有机化学,2012,32(2):382-387. |
| 作者姓名： | 李邦玉 喻龙宝 王耀荣 姚英明 张勇 沈琪 |
| 作者单位： | 1. 苏州市职业大学应用化学研究室 苏州215104 2. 江苏大学化学化工学院 镇江212013 3. 苏州大学材料与化学化工学部 苏州215123 |
| 基金项目： | 苏州市职业大学博士基金，校创新基金，校大学生创新基金 |
| 摘 要： | 无水YbCl3和席夫碱HL=3,5-(t-Bu)2-2-HOC6H2CH=N-8-C9H6N]锂盐按1∶1物质的量比在THF中反应,得到离子对席夫碱镱氯化物YbLCl3Li(DME)3(1).标题配合物1经元素分析、IR光谱和X射线衍射结构表征.配合物1属单斜晶系,P21/n空间群,晶胞参数:a=1.4855(16)nm,b=1.3696(13)nm,c=2.1816(2)nm,α=90.00°,β=98.217(3)°,γ=90.00°,V=4.3748(8)nm3,Z=4,F(000)=1868,Mr=916.17,Dc=1.397 g.cm-3,μ=2.364 mm-1,R1=0.0855,wR2=0.1863. |
| 关 键 词： | 镱 席夫碱 氯化物 合成 晶体结构 离子对 |
Synthesis and Structure of Ion-Pairs Ytterbium Chloride Bearing Tridentate [O,N,N] Schiff-Base Ligand |
|
| Li, Bangyu , Yu, Longbao , Wang, Yaorong , Yao, Yingrning , Zhang, Yong , Shen, Qi.Synthesis and Structure of Ion-Pairs Ytterbium Chloride Bearing Tridentate [O,N,N] Schiff-Base Ligand[J].Chinese Journal of Organic Chemistry,2012,32(2):382-387. | |
| Authors: | Li Bangyu Yu Longbao Wang Yaorong Yao Yingrning Zhang Yong Shen Qi |
| Institution: | Li,Bangyu*,a Yu,Longbaob Wang,Yaorongc Yao,Yingmingc Zhang,Yongc Shen,Qic(a Institute of Applied Chemistry,Suzhou Vocational University,Suzhou 215104)(b Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013)(c Chemical Engineering and Materials Science,Suzhou University,Suzhou 215123) |
| Abstract: | The treatment of Schiff base HL HL=3,5-(t-Bu)2-2-HOC6H2CH=N-8-C9H6N] with 1 equiv.n-BuLi in THF followed by reacting with 1 equiv.YbCl3 gives the ion-pairs ytterbium Schiff base complex YbLCl3Li(DME)3(1).The com-plex 1 was characterized by elemental analysis,IR spectra,and X-ray structural determination.The crystal data of complex 1 are monoclinic,P21/n space group,a=1.4855(16) nm,b=1.3696(13) nm,c=2.1816(2) nm,α=90.00°,β=98.217(3)°,γ=90.00°,V=4.3748(8) nm3,Z=4,F(000)=1868,Mr=916.17,Dc=1.397 g.cm-3,μ=2.364 mm-1,R1=0.0855,wR2=0.1863. |
| Keywords: | ytterbium Schiff-base chloride synthesis crystal structure ion-pairs |
| 本文献已被 CNKI 万方数据 等数据库收录！ | |