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异伍兹烷衍生物的研究进展
引用本文:公绪滨,孙成辉,庞思平,张静,李玉川,赵信岐.异伍兹烷衍生物的研究进展[J].有机化学,2012,32(3):486-496.
作者姓名:公绪滨  孙成辉  庞思平  张静  李玉川  赵信岐
作者单位:北京理工大学 材料学院 北京100081
基金项目:教育部新世纪优秀人才支持计划(No.NCET-09-0046)资助项目~~
摘    要:六硝基六氮杂异伍兹烷(HNIW或CL-20)是当今世界上综合性能最好的单质炸药,在20余年的研究过程中,各国研究者合成出了百余种异伍兹烷衍生物.根据笼体上取代基的不同以及合成反应的类型,系统总结了各类衍生物的合成、用途及反应性.最后对异伍兹烷衍生物的发展方向进行了展望.

关 键 词:异伍兹烷衍生物  高能量密度化合物  综述

Research Progress in Study of Isowurtzitane Derivatives
Gong, Xubin , Sun, Chenghui , Pang, Siping , Zhang, Jing , Li, Yuchuan , Zhao, Xinqi.Research Progress in Study of Isowurtzitane Derivatives[J].Chinese Journal of Organic Chemistry,2012,32(3):486-496.
Authors:Gong  Xubin  Sun  Chenghui  Pang  Siping  Zhang  Jing  Li  Yuchuan  Zhao  Xinqi
Institution:Gong,Xubin Sun,Chenghui Pang,Siping Zhang,Jing Li,Yuchuan Zhao,Xinqi(School of Material Science and Engineering,Beijing Institute of Technology,Beijing 100081)
Abstract:Hexanitrohexaazaisowurtzitane(HNIW or CL-20) is presently the most powerful energetic compound in the world.The synthesis of CL-20 or cage molecules has attracted considerable interest of experts in the area of high-energy materials over the last two decades,and more than 100 isowurtzitane derivatives were synthesized.In this paper,the synthesis,application and reactivity of these compounds are summarized systematically according to different substituents on the cage and types of reactions.The developing tends of isowurtzitane derivatives are also presented.
Keywords:isowurtzitane derivatives  high energy density compound  review
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