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铜胺络合物作用下取代2-萘酚的交叉偶合反应
引用本文:王秀珍,庞冀燕,汪波,许遵乐.铜胺络合物作用下取代2-萘酚的交叉偶合反应[J].有机化学,2005,25(7):859-861.
作者姓名:王秀珍  庞冀燕  汪波  许遵乐
作者单位:中山大学化学与化学工程学院,广州,510275
摘    要:在铜(II)-胺络合物作用下, 取代2-萘酚化合物进行交叉偶合反应, 得到几种结构新颖的取代1,1'-联-2-萘酚化合物, 产率44%~90%. 化合物的结构经过核磁、红外光谱及质谱进行确证.

关 键 词:取代1  1'-联-2-萘酚  铜胺络合物  氧化偶合反应  合成
收稿时间:2004-8-23
修稿时间:2004-1-18

Study on Cross-coupling Reactions of Substituted 2-Naphthols Promosted by Copper(II)-amine Complex
WANG Xiu-zhen,PANG Ji-Yan,WANG Bo,XU Zun-Le.Study on Cross-coupling Reactions of Substituted 2-Naphthols Promosted by Copper(II)-amine Complex[J].Chinese Journal of Organic Chemistry,2005,25(7):859-861.
Authors:WANG Xiu-zhen  PANG Ji-Yan  WANG Bo  XU Zun-Le
Institution:(School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275)
Abstract:The cross-coupling reaction of substituted 2-naphthols in the presence of copper(II)-amine complex was described. Several novel asymmetrically substituted bi-naphthol compounds were obtained in yields of 44%~90%. The structures of these compounds were characterized by 1H NMR, IR and FAB-MS spectra.
Keywords:substituted 1  1'-bi-2-naphthol  copper-amine complex  coupling reaction  synthesis  
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