可见光诱导烷基羧酸及其衍生物的脱羧偶联反应研究进展

烷基羧酸广泛存在于自然界之中,科研工作者一直致力于开发以来源丰富的烷基羧酸及其衍生物作为起始原料的反应.烷基羧酸及其衍生物在可见光氧化还原作用下可以高效地生成烷基自由基,从而在温和条件下用于构筑各类化学键.以可见光催化烷基羧酸及其衍生物的脱羧自由基反应类型为线索,系统地综述了近年来在可见光条件下烷基羧酸及其衍生物的脱羧官能团化反应研究进展.

Progress in Photoinduced Decarboxylative Radical Cross-Coupling of Alkyl Carboxylic Acids and Their Derivatives

Alkyl carboxylic acids are among the most ubiquitous organic molecules found in nature.The reactions using abundant carboxylic acid and its derivatives as starting materials deserve widespread attention over the world.They are often easy to generate alkyl radical by photoredox catalysis under mild conditions for building various chemical bonds in organic chemistry.Based on the reaction modes,decarboxylation of alkylcarboxylic acids and their derivatives,the recent progress in decarboxylation of alkylcarboxylic acids and their derivatives under visible light is reviewed.