| 一些新型呋咱衍生物的合成 |
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| 引用本文： | 潘英明,张业,王恒山,李芳耀,童碧海,唐莅东.一些新型呋咱衍生物的合成[J].有机化学,2006,26(3):314-317. |
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| 作者姓名： | 潘英明 张业 王恒山 李芳耀 童碧海 唐莅东 |
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| 作者单位： | 广西师范大学化学化工学院,桂林,541004 |
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| 基金项目： | 国家自然科学基金(No.20362002)，广西高校百名中青年学科带头人资助计划，广西青年科学基金(No.0229023)资助项目. |
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| 摘 要： | 以歧化松香为原料, 将其纯化得到脱氢松香酸, 然后经甲酯化、溴代、硝化、成环等步骤, 合成了三个新型脱氢松香酸甲酯呋咱的衍生物12,13-氧化呋咱脱异丙基脱氢松香酸甲酯、12,13-呋咱脱异丙基脱氢松香酸甲酯、12-溴-13,14-氧化呋咱脱异丙基脱氢松香酸甲酯. 产物经红外光谱、核磁共振谱和元素分析方法进行了表征.
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| 关 键 词： | 脱氢松香酸 12 13-氧化呋咱脱异丙基脱氢松香酸甲酯 12 13-呋咱脱异丙基脱氢松香酸甲酯 12-溴-13 14-氧化呋咱脱异丙基脱氢松香酸甲酯 |
| 收稿时间： | 03 8 2005 12:00AM |
| 修稿时间： | 09 12 2005 12:00AM |
Synthesis of Some Novel Furazan Derivatives |
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| PAN,Ying-Ming,ZHANG,Ye,WANG,Heng-Shan,LI,Fang-Yao,TONG,Bi-Hai,TANG,Li-Dong.Synthesis of Some Novel Furazan Derivatives[J].Chinese Journal of Organic Chemistry,2006,26(3):314-317. |
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| Authors: | PAN Ying-Ming ZHANG Ye WANG Heng-Shan LI Fang-Yao TONG Bi-Hai TANG Li-Dong |
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| Institution: | College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004 |
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| Abstract: | Starting from dehydroabietic acid, which was purified from disproportionated rosin, three novel heterocycle compounds, methyl 12,13-oxofurazan-deisopropyldehydroabietate, methyl 12,13-furazan- deisopropyldehydroabietate and methyl 12-bromo-13,14-oxofurazan-deisopropyldehydroabietate were syn- thesized through several steps, such as methylation, bromination, nitration and cyclization. All three com- pounds were characterized by IR, 1H NMR, 13C NMR spectra and elemental analyses. |
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| Keywords: | dehydroabietic acid methyl 12 13-oxofurazan-deisopropyldehydroabietate methyl 12 13- furazan-deisopropyldehydroabietate methyl 12-bromo-13 14-oxofurazan-deisopropyldehydroabietate |
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