| N,N'-二茂铁甲基-(1S,2S)-1,2-二苯基乙二胺的合成及其在烯烃的不对称双羟基化反应中的应用 |
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| 引用本文： | 李新生,葛健锋,孔黎春.N,N'-二茂铁甲基-(1S,2S)-1,2-二苯基乙二胺的合成及其在烯烃的不对称双羟基化反应中的应用[J].有机化学,2005,25(11):1487-1489. |
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| 作者姓名： | 李新生 葛健锋 孔黎春 |
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| 作者单位： | [1]江师范大学化学系,金华 321004 [2]州大学材料工程学院,苏州 215006 |
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| 基金项目： | 浙江省金华市科技局资助项目 |
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| 摘 要： | (1S,2S)-1,2-二苯基乙二胺和甲酰基二茂铁经缩合和还原两步反应, 以90%的产率合成了N,N'-二茂铁甲基-(1S,2S)-1,2-二苯基乙二胺, 并以其为配体催化烯烃的不对称双羟基化反应, 获得了较高的对映选择性(71%～86% ee).
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| 关 键 词： | N N'-二茂铁基-(1S 2S)-1 2-二苯基乙二胺 不对称双羟基化反应 手性邻二醇 |
| 收稿时间： | 06 21 2004 12:00AM |
| 修稿时间： | 06 1 2005 12:00AM |
Synthesis of N,N'-Diferrocenyl-methyl-(1S,2S)-1,2-diphenylethane- diamine and Its Application as Chiral Ligand to the AsymmetricDihydroxylation of Olefins |
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| LI,Xin-Sheng,GE,Jian-Feng,KONG,Li-Chun.Synthesis of N,N''-Diferrocenyl-methyl-(1S,2S)-1,2-diphenylethane- diamine and Its Application as Chiral Ligand to the AsymmetricDihydroxylation of Olefins[J].Chinese Journal of Organic Chemistry,2005,25(11):1487-1489. |
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| Authors: | LI Xin-Sheng GE Jian-Feng KONG Li-Chun |
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| Institution: | a.Department of Chemistry and Biology, Zhejiang Normal University, Jinhua 321004;b.Department of Material and Engineering, Suzhou University, Suzhou 215006 |
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| Abstract: | N,N'-Diferrocenylmethyl-(1S,2S)-1,2-diphenylethanediamine was synthe-sized by two steps from (1S,2S)-1,2-diphenylethanediamine and ferrocenealdehyde, and has been used as chiral ligand to asymmetric dihydroxylation of olefins. A good enantioselectivity (71%～86% ee) has been achieved. |
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| Keywords: | N N'-diferrocenylmethyl-(1S 2S)-1 2-diphenylethanediamine asymmetric dihydroxylation chiral vicinal diol |
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