| 有机催化的不对称氧化反应 |
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| 引用本文： | 宫斌,孟庆伟,高占先.有机催化的不对称氧化反应[J].有机化学,2008,28(4):588-597. |
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| 作者姓名： | 宫斌 孟庆伟 高占先 |
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| 作者单位： | 大连理工大学精细化工国家重点实验室,大连,116023 |
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| 摘 要： | 有机催化剂在不对称氧化反应中显示出巨大应用潜力. 综述了不同类型的有机催化剂催化的α,β-不饱和醛酮、烯烃的不对称环氧化反应及羰基化合物的不对称α-羟基化反应, 并对催化特点及催化机理作了详细的描述.
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| 关 键 词： | 有机催化剂 不对称氧化 不对称环氧化 α-羟基化 |
| 收稿时间： | 2006-11-17 |
| 修稿时间： | 2006年11月17 |
Organocatalytic Asymmetric Oxidation |
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| GONG Bin,MENG Qing-Wei,GAO Zhan-Xian.Organocatalytic Asymmetric Oxidation[J].Chinese Journal of Organic Chemistry,2008,28(4):588-597. |
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| Authors: | GONG Bin MENG Qing-Wei GAO Zhan-Xian |
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| Institution: | (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023) |
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| Abstract: | A great application potential of organocatalysts has been displayed in asymmetric oxidation. Asymmetric epoxidation of α,β-unsaturated aldehyde/ketone as well as olefin, and asymmetric α-hydroxylation of carbonyl compounds catalyzed by various types of organocatalysts are reviewed in this paper. The characteristics and mechanism of organocatalysis are also depicted in detail. |
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| Keywords: | organocatalyst asymmetric oxidation asymmetric epoxidation α-hydroxylation |
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