| 钯催化下有机锡化合物的偶联反应在碳-碳键形成过程中的应用 |
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| 引用本文： | 余正坤,王世华.钯催化下有机锡化合物的偶联反应在碳-碳键形成过程中的应用[J].有机化学,1993,13(6):579-589. |
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| 作者姓名： | 余正坤 王世华 |
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| 作者单位： | 中国科学院大连化学物理研究所，中国科学院大连化学物理研究所 辽宁，大连，116023，辽宁，大连，116023 |
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| 摘 要： | 本文述评了最近几年来钯催化的有机锡化合物与有机亲电试剂的交叉偶联反应在有机合成中用于碳-碳键形成的主要研究成果。主要讨论了直接交叉偶联反应,CO或烯键插入的交叉偶联反应和机理。
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| 关 键 词： | 形成过程 碳-碳键 耦合反应 有机锡化合物 钯催化 交叉偶联反应 机理 酰氯 卤化物 |
Formation of carbon-carbon bonds by the palladium-catalyzed cross- coupling reactions of organotins with organic electrophiles |
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| YU Zheng-Kun,WANG Shi-Hua Dalian Institute of Chemical Physics,Academia Sinica, Dalian,Liaoning.Formation of carbon-carbon bonds by the palladium-catalyzed cross- coupling reactions of organotins with organic electrophiles[J].Chinese Journal of Organic Chemistry,1993,13(6):579-589. |
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| Authors: | YU Zheng-Kun WANG Shi-Hua Dalian Institute of Chemical Physics Academia Sinica Dalian Liaoning |
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| Institution: | Dalian Inst Chem Phys, CAS.Dalian(116012) |
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| Abstract: | The important results reported recently on the formation of carbon-carbon bonds bythe palladium-catalyzed cross-coupling reactions of organotins with organic electrophileswere reviewed. The direct cross-coupling reactions. the indirect ones with insertions of CO oralkenvl bonds and the mechanisms were discussed. The content is arranged according to the cate-gories of organic electrophiles |
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| Keywords: | Palladium-catalyzed organotin compounds cross-coupling formation of carboncarbon bonds |
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