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有机二阶非线性光学发色团的研究进展
引用本文:李倩倩,秦金贵,李振.有机二阶非线性光学发色团的研究进展[J].有机化学,2011,31(9).
作者姓名:李倩倩  秦金贵  李振
作者单位:武汉大学化学与分子科学学院 湖北省有机高分子光电功能材料重点实验室 武汉430072
基金项目:国家自然科学基金(No.21034006)资助项目
摘    要:近年来,科学家们通过引进杂环片段、采用双(或多)官能化以及运用分子间弱相互作用等方法,在二阶非线性光学发色团的性能优化方面取得了较大进展.结合本课题组的研究,对此领域的研究进行了较全面的综述,并特别针对“非线性-透光性”矛盾的解决途径进行了较为详细的介绍.

关 键 词:二阶非线性光学效应  有机发色团  分子一阶超极化率  透明性

Recent Progress of Organic Second-Order Nonlinear Optical Chromophores
Li Qianqian,Qin Jingui,Li Zhen.Recent Progress of Organic Second-Order Nonlinear Optical Chromophores[J].Chinese Journal of Organic Chemistry,2011,31(9).
Authors:Li Qianqian  Qin Jingui  Li Zhen
Institution:Li,Qianqian Qin,Jingui Li,Zhen*(Hubei Key Laboratory on Organic and Polymeric Opto-Electronic Materials,Department of Chemistry,Wuhan University,Wuhan 430072)
Abstract:Second-order nonlinear optical(NLO) materials have played a very important role in laser technology since the invention of laser.As to the organic NLO materials,the chromophores are the key component.To tune the nonlinearity-transparency trade-off in organic NLO chromophores,several promising strategies were attempted,including the introduction of heterocyclic rings,dual(mutiple) functionalizations and utilization of the interactions between chromophore moieties.In this article,recent progress in this field...
Keywords:second-order nonlinear optical effect  chromophore  molecular first-order hyperpolarizability  transparency  
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