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含酰胺和席夫碱单元的杯[4]芳烃衍生物的合成与配合性能
引用本文:杨发福,蔡秀琴,郭红玉,陈希磊.含酰胺和席夫碱单元的杯[4]芳烃衍生物的合成与配合性能[J].有机化学,2005,25(5):545-548.
作者姓名:杨发福  蔡秀琴  郭红玉  陈希磊
作者单位:1. 福建师范大学化学与材料学院,福州,350007;中国科学院福建省物质结构研究所结构化学国家重点实验室,福州,350007
2. 福建师范大学化学与材料学院,福州,350007
基金项目:中国科学院资助项目,福建省自然科学基金,国家重点实验室基金
摘    要:杯4]-1,3-二乙酸乙酯衍生物1与水合肼反应生成杯4]芳烃酰肼衍生物2, 然后进一步与相应的芳醛反应, 高产率地合成了三个新型的含酰胺和席夫碱单元的杯4]芳烃衍生物3a3c和一例新型杯4]冠醚4. 阳离子萃取实验表明新型杯芳烃衍生物比只含有酰胺基或席夫碱基的杯芳烃衍生物有更强的软金属离子配合性能, 杯4]冠醚4还对Ag有较好的选择性萃取能力.

关 键 词:杯[4]芳烃  酰胺  席夫碱  配合
收稿时间:2004-7-1
修稿时间:2004-11-15

Syntheses and Complexation Properties of Calix[4]arene Derivatives Containing Amides and Schiff-base Units
YANG Fa-Fu,CAI Xiu-Qin,GUO Hong-Yu,CHEN Xi-Lei.Syntheses and Complexation Properties of Calix[4]arene Derivatives Containing Amides and Schiff-base Units[J].Chinese Journal of Organic Chemistry,2005,25(5):545-548.
Authors:YANG Fa-Fu  CAI Xiu-Qin  GUO Hong-Yu  CHEN Xi-Lei
Institution:( Department of Chemistry, Fujian Normal University, Fuzhou 350007)( State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002)
Abstract:Calix4]arene hydrazide derivative 2 was obtained by the reaction of 1,3-bis(ethoxycarbonyl- methoxy)calix4]arene (1) with hydrazine hydrate. Treatment of compound 2 with corresponding aldehydes, three novel calix4]arene derivatives 3 and a new calix4]crown 4 containing amides and schiff-base units were synthesized in high yields. The extraction experiments showed that new calix4]arene derivatives ex- hibited higher complexation abilities than calix4]arene derivatives containing amides or schiff-bases. Calix4]crown 4 showed high Ag complexation selectivity.
Keywords:calix[4]arene  amide  schiff-base  complexation
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