| 含1,3,4-噻二唑α-氨基膦酸酯的合成及其表征 |
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| 引用本文： | 武现丽,高伟霞,马兵,王珍,韩超,曹书霞,廖新成.含1,3,4-噻二唑α-氨基膦酸酯的合成及其表征[J].有机化学,2009,29(9):1429-1433. |
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| 作者姓名： | 武现丽 高伟霞 马兵 王珍 韩超 曹书霞 廖新成 |
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| 作者单位： | 郑州大学化学系河南省化学生物与有机化学重点实验室,郑州,450052 |
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| 摘 要： | 以硫代氨基脲为前体原料, 合成了两种2位为不同烷硫基的5-氨基-1,3,4噻二唑, 采用“一锅煮”的方法, 与不同的醛及亚磷酸酯合成了一系列含1,3,4-噻二唑的α-氨基磷酸酯, 所得产物均经IR, MS, 1H NMR, 31P NMR和元素分析确证结构.
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| 关 键 词： | 噻二唑 α-氨基膦酸酯 亚磷酸酯 一锅煮 |
| 收稿时间： | 2008-10-14 |
| 修稿时间： | 2009-1-12 |
Synthesis and Characterization of α-Aminophosphonates Containing 1,3,4-Thiadiazole |
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| Wu Xianli,Gao Weixia,Ma Bing,Wang Zhen,Han Chao,Cao Shuxia,Liao Xincheng.Synthesis and Characterization of α-Aminophosphonates Containing 1,3,4-Thiadiazole[J].Chinese Journal of Organic Chemistry,2009,29(9):1429-1433. |
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| Authors: | Wu Xianli Gao Weixia Ma Bing Wang Zhen Han Chao Cao Shuxia Liao Xincheng |
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| Institution: | (Key Laboratory of Chemical Biology and Organic Chemistry, Department pf Chemistry,
Zhengzhou University, Zhengzhou 450052)
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| Abstract: | A series of α-aminophosphonates containing a 1,3,4-thiadiazole moiety were synthesized by a one-pot multicomponent reaction of two different 2-alkylsulfanyl-5-amino-1,3,4-thiadiazoles synthesized from thiosemicarbazide, with different aldehydes and phosphates. The structures of these compounds were confirmed by IR, MS, 1H NMR, 31P NMR techniques and elemental analyses. |
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| Keywords: | thiadiazole α-aminophosphonate phosphate one pot |
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