| Heck反应最新研究进展 |
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| 引用本文： | 王宗廷,张云山,王书超,夏道宏.Heck反应最新研究进展[J].有机化学,2007,26(2):143-152. |
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| 作者姓名： | 王宗廷 张云山 王书超 夏道宏 |
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| 作者单位： | 中国石油大学(华东)化学化工学院重质油加工国家重点实验室,东营,257062 |
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| 摘 要： | Heck反应是一类重要的卤代芳烃烯基化、形成新的C—C键的合成反应, 近几年来一直是催化化学和有机化学的研究热点. 总结了最近几年来国内外Heck反应新型催化体系、不对称Heck反应、Heck反应在有机合成中的最新应用等重要研究成果, 希望引起同行对Heck反应的关注.
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| 关 键 词： | Heck反应 钯 催化 不对称合成 应用 |
| 收稿时间： | 2005-8-17 |
| 修稿时间： | 2005-08-17 |
Recent Progress in Heck Reaction |
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| WANG Zong-Ting,ZHANG Yun-Shan,WANG Shu-Chao,XIA Dao-Hong.Recent Progress in Heck Reaction[J].Chinese Journal of Organic Chemistry,2007,26(2):143-152. |
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| Authors: | WANG Zong-Ting ZHANG Yun-Shan WANG Shu-Chao XIA Dao-Hong |
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| Institution: | State Key Laboratory of Heavy Oil Processing, School of Chemistry and Chemical Engineering, China University of Petroleum (East China |
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| Abstract: | Heck reaction is a sort of classical methodology of the vinylation of aryl halides for the construction of new C--C bond. The new efficient catalysts for Heck reaction and the applications in whole synthesis of natural production have been developed greatly these years. In this paper, the recent progress in Heck coupling reaction including catalytic systems, asymmetric syntheses and applications in organic chemistry is reviewed. |
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| Keywords: | Heck reaction palladium catalysis asymmetric synthesis application |
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