| 双（亚烷二硫基)四硫富瓦烯衍生物的合成及其电化学性质 |
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| 引用本文： | 迟兴宝,李有桂,蒋昌盛.双（亚烷二硫基)四硫富瓦烯衍生物的合成及其电化学性质[J].有机化学,2002,22(11):873-878. |
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| 作者姓名： | 迟兴宝 李有桂 蒋昌盛 |
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| 作者单位： | 1. 淮北煤炭师范学院化学系,淮北,235000
2. 中国科学技术大学化学系,合肥,230000 |
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| 摘 要： | 以四(氰乙硫基)四硫富瓦烯为原料经醇钠消去氰乙基生成四硫富瓦烯四硫盐， 再与二元卤代烷烃化反应，除了得到三种文献报道的双(亚烷二硫基)四硫富瓦烯衍 生物外，还得到三种新的“四桥”双—四硫富瓦烯衍生物，为“桥式”双—四硫富 瓦烯衍生物的合成提出了一种新的方法．并研究了它们的循环伏安图、电化学性质 和紫外—可见光光谱．
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| 关 键 词： | 四硫富瓦烯 醇钠 电化学 衍生物 紫外光谱学 |
| 修稿时间： | 2001年12月31 |
Synthesis and electrochemical behaviour of bis(alkylenedithio) tetrathiafulvalenes |
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| CHI,Xing-Bao a LI,You-Gui b JIANG,Chang-Sheng b.Synthesis and electrochemical behaviour of bis(alkylenedithio) tetrathiafulvalenes[J].Chinese Journal of Organic Chemistry,2002,22(11):873-878. |
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| Authors: | CHI Xing-Bao a LI You-Gui b JIANG Chang-Sheng b |
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| Institution: | Department of Chemistry, Huaibei Coal Teachers College,Huaibei (235000);Department of Chemistry, University of Science and Technology of China,Hefei(230000) |
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| Abstract: | 2,3,6,7-Tetrakis(2'-cyanoethylthio)-tetrathiafulvalene was treated with sodium alkoxide to give tetrathiafulvalene-2,3,6,7-tetranthiolate. The generated thiolate was trapped by subsequent quenching with dibromoalkylane, yielding the corresponding bis(alkylenedithio) compounds and four-bridged bistetrathiafulvalenes. Their electrochemical properties of bis(alkylenedithio) tetrathiafulvalene and four-bridged bis-tetrathiafulvalenes were studied by cyclic voltammetry. UV/vis spectra of these compounds are also discussed. |
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| Keywords: | tetrathiafulvalene sodium alkoxide ELECTROCHEMISTRY DERIVATIVES ULTRAVIOLET SPECTROSCOPY |
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