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Radioactive Tracer Study of the Displacement of Iodine Adatoms from Platinized Platinum Electrode by Carbon Monoxide
Authors:Andreev  V N  Kolyadko  E A  Podlovchenko  B I
Institution:(1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia;(2) Faculty of Chemistry, Moscow State University, Vorob'evy Gory 1, Moscow, 119992, Russia
Abstract:Radioactive tracer studies confirm the earlier electrochemical results that carbon monoxide can virtually completely displace iodine adatoms. For the first time, it is found that iodine adatoms are not displaced by carbon monoxide when iodide anions are adsorbed in the presence of an upd silver monolayer. The possible reasons for the effect observed are discussed.
Keywords:radioactive tracer technique  platinized platinum  iodine adatoms  silver adatoms  carbon monoxide
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