Electrochemical synthesis of peroxodisulfates from dilute sulfate solutions for detoxification of biological media |
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Authors: | A K Evseev M Sh Khubutiya M M Gol’din A G Volkov A A Koldaev |
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Institution: | (1) Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125190, Russia;(2) Sklifosovskii Institute of Emergency Medical Care, Moscow, Russia;(3) Oakwood College, Huntsville, USA |
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Abstract: | The method of indirect electrochemical generation of active oxygen in the persulfate form is developed. It is based on the oxidation of dilute aqueous sulfate solutions and can be used in the hypoxic states therapy. Data on the relationship between the biological activity of synthesized persulfate solutions and their electrosynthesis parameters and redox potentials are used for optimization of electrosynthesis conditions. Bloodcompatible oxidation solutions capable of detoxifying blood containing endo-and exotoxicants are synthesized. |
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Keywords: | electrosynthesis active oxygen detoxification blood redox potential |
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