首页 | 本学科首页   官方微博 | 高级检索  
     检索      


The limiting current of electrochemical reaction in the binary electrolyte in the rotating electrochemical cell
Authors:D A Bograchev  A D Davydov
Institution:(1) Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
Abstract:A rotating cylindrical electrochemical cell with a plane ring electrode on its cover containing a binary electrolyte was considered. The equation for the diffusion limiting current density on the ring electrode was derived ignoring the effect of Coriolis force. The solution of transfer equations by the Karman method at the limiting current in the cell allowed us to analyze the effect of Coriolis force on the boundary layer thickness and to determine the conditions, under which the Coriolis force may be ignored.
Keywords:rotating electrochemical cell  diffusion limiting current  Coriolis force  the Karman method
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号