The limiting current of electrochemical reaction in the binary electrolyte in the rotating electrochemical cell |
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Authors: | D A Bograchev A D Davydov |
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Institution: | (1) Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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Abstract: | A rotating cylindrical electrochemical cell with a plane ring electrode on its cover containing a binary electrolyte was considered. The equation for the diffusion limiting current density on the ring electrode was derived ignoring the effect of Coriolis force. The solution of transfer equations by the Karman method at the limiting current in the cell allowed us to analyze the effect of Coriolis force on the boundary layer thickness and to determine the conditions, under which the Coriolis force may be ignored. |
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Keywords: | rotating electrochemical cell diffusion limiting current Coriolis force the Karman method |
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