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Voltammetric study of the behaviour of N-acetyl-p-aminophenol in aqueous solutions at a platinum electrode
Institution:Lodz University of Technology, Faculty of Chemistry, Institute of General and Ecological Chemistry, ul. Zeromskiego 116, 90-924 Lodz, Poland
Abstract:The electrochemical oxidation of N-acetyl-p-aminophenol (PAR) was investigated at a Pt electrode with the application of cyclic (CV) and differential pulse (DPV) voltammetry methods. An effect of scan rate, substrate concentration and pH on electrode reactions was determined. The parameters of substrate electro-oxidation, i.e. heterogeneous rate constant, charge transfer coefficient, and diffusion coefficient, were calculated. Our investigation's results prove the exchange of two electrons and one proton in the first step, followed by a chemical reaction. PAR electro-oxidation occurs according to an EC mechanism.
Keywords:Platinum electrode  Electro-oxidation  EC mechanism
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