| 四苯基卟啉钴催化有机化合物与二氧化碳的电羧化反应Ⅱ. |
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| 引用本文： | 郑国栋,佟珊玲.四苯基卟啉钴催化有机化合物与二氧化碳的电羧化反应Ⅱ.[J].应用化学,1994,11(5):27-30. |
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| 作者姓名： | 郑国栋 佟珊玲 |
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| 作者单位： | 吉林大学化学系，吉林大学环境化学系，长春市轻工业学校，湖南大学化工系 |
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| 基金项目： | 吉林省科委青年基金,国家自然科学基金和国家教委博士点基金资助项目 |
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| 摘 要： | 研究了α、β、γ、δ－四苯基卟啉钴（ＣｏＴＰＰ）存在下苄基氯、苯乙酮、二苯甲酮和萘等与ＣＯ＿２的电羧化反应，与无催化剂体系相比，ＣｏＴＰＰ可使这些有机化合物与ＣＯ＿２电羧化反应的过电位降低约８００～１０００ｍＶ，对反应有较高的催化活性．用ＵＶ，ＩＲ和ＧＣ－ＭＳ确认了电羧化产物，并探讨了ＣｏＴＰＰ催化反应机理．
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| 关 键 词： | 卟啉钴，苄基氯，苯二酮，二苯甲酮，萘，催化电羧化反应 |
| 收稿时间： | 1993-10-27 |
Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrin Ⅱ. |
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| Zheng Guodong,Yan Yan and Gao Sai.Electrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrin Ⅱ.[J].Chinese Journal of Applied Chemistry,1994,11(5):27-30. |
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| Authors: | Zheng Guodong Yan Yan and Gao Sai |
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| Abstract: | The CoTPP showed an effective catalytic activity in electrocarboxylation of benzylchloride,acetophnone,benzophenone and naphthalene with CO2.The products of electro-carboxvlation were characterized by UV,IR and GC-MS measurements,The mechanisms ofthe catalvtic electrocarboxylation have been discussed. |
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| Keywords: | cobaltoporphyrin benzyl chloride acetophenone benzophenone naphthalene catalvtic electrocarboxylation |
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