| 铁酸铜负极材料的微波合成和电化学性能 |
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| 引用本文： | 王锋,胡新良,张鹏,赵双琪,丁瑜.铁酸铜负极材料的微波合成和电化学性能[J].应用化学,2015,32(10):1184-1189. |
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| 作者姓名： | 王锋 胡新良 张鹏 赵双琪 丁瑜 |
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| 作者单位： | 湖北工程学院化学与材料科学学院 湖北 孝感 432000; 华中科技大学材料科学与工程学院 武汉 430074 |
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| 基金项目： | 国家自然科学基金(21301045,51402096)、湖北省教育厅青年项目(20701005)和湖北省科技厅面上项目(2012BFF00503) |
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| 摘 要： | 以十六烷基三甲基溴化铵(CTAB)为模板,硝酸铁和硝酸铜为起始物,采用一步微波法,再经过简单的热处理制备了CuFe2O4负极材料,采用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶红外光谱(FT-IR)等测试技术表征材料的结构和形貌。 电化学测试表明,在100 mA/g电流密度,0.01~3.0 V电压条件下,材料的首周嵌脱锂比容量分别为1202.2和873.2 mA·h/g,循环50周后,嵌锂比容量仍保持在近650 mA·h/g,显示出优异的电化学性能。
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| 关 键 词： | 微波反应 电化学性能 铁酸铜 锂离子电池 |
| 收稿时间： | 2015-03-17 |
Microwave Assisted Synthesis and Electrochemical Performance of Copper Ferrite as Anode Material for Lithium-ion Battery |
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| WANG Feng,HU Xinliang,ZHANG Peng,ZHAO Shuangqi,DING Yu.Microwave Assisted Synthesis and Electrochemical Performance of Copper Ferrite as Anode Material for Lithium-ion Battery[J].Chinese Journal of Applied Chemistry,2015,32(10):1184-1189. |
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| Authors: | WANG Feng HU Xinliang ZHANG Peng ZHAO Shuangqi DING Yu |
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| Institution: | College of Chemistry and Materials Science,Hubei Engineering University,Xiaogan,Hubei 432000,China; School of Materials Science and Engineering,Huazhong University of Science and Technology,Wuhan 430074,China |
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| Abstract: | The copper ferrite was prepared by an one-pot microwave assisted sintering process with cetrimonium bromide(CTAB) as the template and copper and ionic nitrates as the reactants. The morphology and microstructure of the products were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), and FT-IR spectroscopy. The as-prepared CuFe2O4 exhibits excellent electrochemical performance with the lithiation/delithiation capacity of 1202.2 mA·h/g and 873.2 mA·h/g(at the current 100 mA/g), respectively, and the capacities are maintained over 650 mA·h/g even after 50 charge/discharge cycles. |
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| Keywords: | microwave synthesis electrochemical performance ferrite lithium ion battery |
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