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炭载微过氧化物酶-11电极对O2和H2O2还原的电催化性能
引用本文:李旭光,高颖,冯玉英,邢巍,杨辉,陆天虹.炭载微过氧化物酶-11电极对O2和H2O2还原的电催化性能[J].应用化学,2002,19(3):285-0.
作者姓名:李旭光  高颖  冯玉英  邢巍  杨辉  陆天虹
作者单位:1. 中国科学院长春应用化学研究所,长春
2. 哈尔滨师范大学化学系,哈尔滨
3. 南京师范大学化学系,南京,210097
基金项目:科技部“973”(G2 0 0 0 0 2 64 0 8),国家自然科学基金 (2 9973 0 15 ),黑龙江省自然科学基金 (B2 0 0 0 -0 6),江苏省教委自然科学基金(0 0 KJB5 0 0 0 7)资助项目
摘    要:氧还原;生物燃料电池;炭载微过氧化物酶-11电极对O2和H2O2还原的电催化性能

关 键 词:氧还原  生物燃料电池  炭载微过氧化物酶-11电极对O2和H2O2还原的电催化性能
文章编号:1000-0518(2002)03-0285-05
收稿时间:2009-06-29
修稿时间:2001年8月21日

Electrocatalytic Behavior of Microperoxidase-11 Adsorbed on Active Carbon for Reduction of Oxygen and Hydrogen Peroxide
LI Xu Guang a,GAO Ying b,FENG Yu Ying c,XING Wei a,YANG Hui c,LU Tian Hong c.Electrocatalytic Behavior of Microperoxidase-11 Adsorbed on Active Carbon for Reduction of Oxygen and Hydrogen Peroxide[J].Chinese Journal of Applied Chemistry,2002,19(3):285-0.
Authors:LI Xu Guang a  GAO Ying b  FENG Yu Ying c  XING Wei a  YANG Hui c  LU Tian Hong c
Institution:LI Xu Guang a,GAO Ying b,FENG Yu Ying c,XING Wei a,YANG Hui c,LU Tian Hong c *
Abstract:Microperoxidase 11(MP 11) was adsorbed on active carbon by equilibrium adsorption method. The electrocatalytic behaviors of MP 11/C electrode for the reduction of O 2 and H 2O 2 were studied by cyclic voltammmetry and linear voltammmetry and RDE technique. The results showed that MP 11/C possessed good electrocatalytic activity for the reduction of O 2 and H 2O 2. And the mechanism of oxygen reduction is dependent on pH of the solution. It provides a reliable method for immobilization of enzymes and a promising catalyst for the reduction of O 2 in biofuel cell.
Keywords:microperoxide  11  oxygen  hydrogen peroxide  reduction  biofuel cell
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