| 大基团取代不对称茂钛（Ⅳ）化合物的合成 |
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| 引用本文： | 舒学军,贺峥杰.大基团取代不对称茂钛（Ⅳ）化合物的合成[J].应用化学,1997,14(2):99-101. |
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| 作者姓名： | 舒学军 贺峥杰 |
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| 作者单位： | 南开大学元素有机化学研究所 |
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| 摘 要： | 大基团取代不对称茂钛（Ⅳ）化合物的合成舒学军贺峥杰＊陈寿山（南开大学元素有机化学研究所天津３０００７１）关键词有机锂，富烯，茂钛化合物，合成１９９６－０６－１９收稿，１９９６－１２－３１修回国家自然科学基金资助课题取代茂钛化合物常常是烯烃异构化的良好...
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| 关 键 词： | 有机锂 富烯 茂钛化合物 合成 |
| 收稿时间： | 1996-06-19 |
Synthesis of Substituted Asymmetric Titanocenes with Bulky Substituents |
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| Shu Xuejun,He Zhengjie ,Chen Shoushan.Synthesis of Substituted Asymmetric Titanocenes with Bulky Substituents[J].Chinese Journal of Applied Chemistry,1997,14(2):99-101. |
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| Authors: | Shu Xuejun He Zhengjie Chen Shoushan |
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| Institution: | Shu Xuejun,He Zhengjie *,Chen Shoushan |
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| Abstract: | A series of substituted cyclopentadienyllithium were prepared from exocyclic double bond addition reaction of 6,6 dialkylfulvenes and 6,6 polymethylenefulvenes with n pentyllithium, 1 cyclohexenyllithium, 1,4 butylenedilithium and 1,6 hexylenedilithium, respectively. Reacting with CpTiCl 3, they gave seventeen novel asymmetric titanocenes with bulky substituents. A general route for preparation of asymmetric titanocenes is herein reported. |
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| Keywords: | organolithium fulvene titanocene synthesis |
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