| 改性沸石H-BEA催化4-苯基丁酸分子内付克反应合成1-萘满酮 |
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| 引用本文： | 邱俊,王建刚,孙杰.改性沸石H-BEA催化4-苯基丁酸分子内付克反应合成1-萘满酮[J].应用化学,2011,28(2):194-198. |
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| 作者姓名： | 邱俊 王建刚 孙杰 |
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| 作者单位： | (吉林化工学院化学与制药工程学院 吉林 132022) |
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| 摘 要： | 以乙二胺四乙酸二钠（EDTA）、柠檬酸、草酸、酒石酸改性制备了H-BEA，并根据XRD和NH3-TPD对沸石H-BEA进行表征。 采用上述改性沸石催化4-苯基丁酸分子内付克反应合成1-萘满酮进行催化剂反应活性评价。 实验结果表明，以柠檬酸改性沸石H-BEA具有较高的催化活性。 进一步对催化剂用量、反应温度、反应时间等工艺条件优化得到最佳工艺条件，在最佳工艺条件下，产物1-萘满酮产率达到94.3%。
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| 关 键 词： | 苯基丁酸 萘满酮 分子内Friedel-Crafts 沸石H-BEA |
| 收稿时间： | 2010-06-25 |
| 修稿时间： | 2010-08-20 |
Synthesis of 1-Tetralones by Intramolecular Friedel-Crafts Reaction of 4-Phenylbutyric Acids Using Modified Zeolite H-BEA |
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| QIU Jun,WANG Jiangang,SUN Jie.Synthesis of 1-Tetralones by Intramolecular Friedel-Crafts Reaction of 4-Phenylbutyric Acids Using Modified Zeolite H-BEA[J].Chinese Journal of Applied Chemistry,2011,28(2):194-198. |
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| Authors: | QIU Jun WANG Jiangang SUN Jie |
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| Institution: | (College of Chemistry and Pharmaceutical Engineering,Jilin Institute of Chemical Technology,Jilin 132022) |
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| Abstract: | Zeolite H-BEA modified by ethylene diamine tetraacetic acid(EDTA),citric acid,oxalic acid,and tartaric acid were prepared and characterized by XRD and NH3-TPD.The catalytic performance was evaluated in the synthesis of 1-tetralone by intramolecular Friedel-Crafts reaction of 4-phenylbutyric acids.Zeolites H-BEA modified by citric acid showed high catalytic activity.In addition,the reaction conditions such as catalyst amount,reaction temperature and reaction time were examined for the optimal process conditi... |
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| Keywords: | phenylbutyric acids tetralones intramolecular Friedel-Crafts zeolites H-BEA |
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