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Zn2+型磺酸树脂对维生素B12的配位吸附及洗脱性能
引用本文:李家政,史作清,范云鸽.Zn2+型磺酸树脂对维生素B12的配位吸附及洗脱性能[J].应用化学,2002,19(10):946-0.
作者姓名:李家政  史作清  范云鸽
作者单位:南开大学,河北工业大学
基金项目:国家自然科学基金资助项目 (2 99740 15 )
摘    要:原位吸附;分离;Zn2+型磺酸树脂对维生素B12的配位吸附及洗脱性能

关 键 词:原位吸附  分离  Zn2+型磺酸树脂对维生素B12的配位吸附及洗脱性能  
文章编号:1000-0518(2002)10-0946-04
收稿时间:2009-06-29
修稿时间:2002年3月7日

Coordination Adsorption of VB12 on D72Zn2+ Resin and Its Elution
LI Jia Zheng a,b,SHI Zuo Qing a ,FAN Yun Ge a.Coordination Adsorption of VB12 on D72Zn2+ Resin and Its Elution[J].Chinese Journal of Applied Chemistry,2002,19(10):946-0.
Authors:LI Jia Zheng a  b  SHI Zuo Qing a  FAN Yun Ge a
Institution:LI Jia Zheng a,b,SHI Zuo Qing a *,FAN Yun Ge a
Abstract:The coordination adsorption resins were prepared by loading different transition metal ions on macroporous sulphonic resin(D72) and acrylic acid resin(D152) respectively, and the coordination adsorption of VB 12 on the resins in various media has been investigated. The sulphonic resin loaded with Zn 2+ (D72Zn 2+ ) was found to possess the best adsorption and desorption properties. The adsorption isotherm of VB 12 on D72Zn 2+ resin in ethanol fits the Langmuir adsorption equation, and the saturated adsorption capacity from ethanol reaches 61 mg/g. The leakage capacity by column operation was 34 mg/g and water appeared an effective eluant with 94% desorption percentage.
Keywords:VB    12    coordination adsorption  sulphonic resin  separation  
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