| 癸二酸己二醇酯/己二酸二醇酯共聚物的合成及热性能 |
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| 引用本文： | 孙杰,李晓萌,罗运军,谭惠民.癸二酸己二醇酯/己二酸二醇酯共聚物的合成及热性能[J].应用化学,2004,21(11):1193-1195. |
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| 作者姓名： | 孙杰 李晓萌 罗运军 谭惠民 |
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| 作者单位： | 北京理工大学，中国工程物理研究院 |
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| 摘 要： | 癸二酸己二醇酯/己二酸二醇酯共聚物的合成及热性能;直接聚合;可降解聚合物
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| 关 键 词： | 癸二酸己二醇酯/己二酸二醇酯共聚物的合成及热性能 直接聚合 可降解聚合物 |
| 文章编号： | 1000-0518(2004)11-1193-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2003年11月28 |
Synthesis and Thermal Property of Poly(hexylene-sebacate)-co-(hexylene-adipate) |
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| SUN Jie a,b ,LI Xiao Meng a,LUOYun Jun a,TAN Hui Min a.Synthesis and Thermal Property of Poly(hexylene-sebacate)-co-(hexylene-adipate)[J].Chinese Journal of Applied Chemistry,2004,21(11):1193-1195. |
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| Authors: | SUN Jie a b LI Xiao Meng a LUOYun Jun a TAN Hui Min a |
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| Institution: | SUN Jie a,b *,LI Xiao Meng a,LUOYun Jun a,TAN Hui Min a |
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| Abstract: | Biodegradable poly(hexylene sebacate) co (hexylene adipate) with high intrinsic viscosity was synthesized by one pot polycondensation of sebacic acid and adipic acid with 1,6 hexylenediol in a yield of 96%. The chemical structure of the copolymer was characterized by FTIR and 1 H NMR. The DSC result shows that the melting point and crystallization temperature of the copolymer decreased with the increase in HA content, and both exhibit the minimum values while x (HA) reachs 60%. It was also found by TG that PHA in the copolymer was easier decomposed, but no effect on the thermal decomposition of PHSe was observed on the copolymerization. |
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| Keywords: | poly(hexylene sebacate)-co-(hexylene-adipate) direct polycondensation thermal decomposition biodegradable polymer |
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