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Sr2+-TiO2薄膜的制备及超亲水性
引用本文:申树芳,刘秀芹,徐承天,陈邦林.Sr2+-TiO2薄膜的制备及超亲水性[J].应用化学,2010,27(1):74-77.
作者姓名:申树芳  刘秀芹  徐承天  陈邦林
作者单位:华东师范大学,化学系,上海,200062
摘    要:以钛酸丁酯作为前驱物,采用溶胶-凝胶法及浸渍-提拉法在载玻片上制备SrO-TiO2薄膜。通过X射线衍射和红外光谱等测试技术表征了SrO-TiO2粉末的结构,用紫外可见分光光度计测定薄膜的透光率,用接触角测试仪测定水与薄膜的接触角。结果表明,掺杂适量Sr2+后,SrO-TiO2粉末中TiO2晶粒的尺寸变小,SrO-TiO2薄膜表面吸附的羟基含量增多且稳定,可提高TiO2薄膜的超亲水性。经紫外光照1h或自然光照5h后,掺杂Sr2+(摩尔分数))为1.0%的SrO-TiO2薄膜与水的接触角接近于0°,表现出良好的亲水性。

关 键 词:TiO2膜,超亲水性,Sr2  掺杂,接触角
收稿时间:2008-12-25
修稿时间:2009-07-09

Preparation and Superhydrophilicity of Sr2+ Doped TiO2 Films
SHEN Shu-Fang,LIU Xiu-Qin,XU Cheng-Tian,CHEN Bang-Lin.Preparation and Superhydrophilicity of Sr2+ Doped TiO2 Films[J].Chinese Journal of Applied Chemistry,2010,27(1):74-77.
Authors:SHEN Shu-Fang  LIU Xiu-Qin  XU Cheng-Tian  CHEN Bang-Lin
Institution:Department of Chemistry,East China Normal University,Shanghai 200062
Abstract:SrO-TiO2 films on glass slides were prepared via sol-gel process and dip-coating technique using tetrabutyl titanate as a precursor.The structure of SrO-TiO2 powder was characterized by XRD and IR.The transmission rates of the films were measured by UV-Vis spectroscopy.The water contact angles of the films were also measured.The results obtained are as follows:the grain size of TiO2 in the SrO-TiO2 powder became smaller when a proper amount of Sr2+ was introduced.The hydroxyl content on the surface of the t...
Keywords:TiO_2 film  superhydrophilicity  Sr~(2+) doping  contact angle
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