| HDPE氯化原位接枝MAH及产物结构 |
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| 引用本文： | 林意生,李莉莉,赵季若,殷敬华.HDPE氯化原位接枝MAH及产物结构[J].应用化学,2005,22(12):1282-0. |
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| 作者姓名： | 林意生 李莉莉 赵季若 殷敬华 |
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| 作者单位： | a高分子物理与化学国家重点实验室，中国科学院长春应用化学研究所；b中国科学院研究生院；c橡塑材料与工程教育部重点实验室，青岛科技大学高分子科学与工程学院 |
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| 基金项目： | 国家自然科学基金重大项目(50390090)，面上项目(50373042)资助 |
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| 摘 要： | HDPE氯化原位接枝MAH及产物结构;高密度聚乙烯;氯化原位接枝;CPE-g-MAH;接枝率;凝胶
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| 关 键 词： | HDPE氯化原位接枝MAH及产物结构 高密度聚乙烯 氯化原位接枝 CPE-g-MAH 接枝率 凝胶 |
| 文章编号： | 1000-0518(2005)12-1282-05 |
| 收稿时间： | 01 9 2005 12:00AM |
| 修稿时间： | 05 10 2005 12:00AM |
In-situ Chlorinating and MAH Grafting on Molecular Chains of High Density Polyethylene |
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| LIN Yi-Sheng,LI Li-Li,ZHAO Ji-Ruo,YIN Jing-Hua.In-situ Chlorinating and MAH Grafting on Molecular Chains of High Density Polyethylene[J].Chinese Journal of Applied Chemistry,2005,22(12):1282-0. |
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| Authors: | LIN Yi-Sheng LI Li-Li ZHAO Ji-Ruo YIN Jing-Hua |
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| Institution: | LIN Yi-Sheng~ |
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| Abstract: | MAH grafted polyethylene was prepared by means of in-situ reaction of HDPE in solid state with chlorine and MAH simultaneously.FTIR and ~(1)H NMR were used to verify the(formation) of the target(copolymer) and to characterize its chemical structure.A quantitative method was developed to(measure) the grafting degree of MAH by virtue of chemical titration and FTIR.The prepared copolymer had a higher grafting degree(up to 2.6% by mass) compared to the MAH grafted PE by conventional methods,and was not crosslinked as proved via the determination of the gel percentage of the grafted samples. |
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| Keywords: | high density polyethylene in-situ chlorinated grafting reaction CPE-g-MAH grafting degree gel |
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