| 以硝基、氨基修饰改性聚苯醚 |
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| 引用本文： | 潘雁,黄玉惠,丛广民.以硝基、氨基修饰改性聚苯醚[J].应用化学,1996,0(5):10-13. |
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| 作者姓名： | 潘雁 黄玉惠 丛广民 |
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| 作者单位： | 中国科学院广州化学研究所 广州 510650 |
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| 基金项目： | 国家自然科学基金,国家科委国家基础性研究重大关键项目 |
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| 摘 要： | 将聚苯醚硝化、还原,分别合成了硝化聚苯醚和胺化聚苯醚,最高硝基、氨基取代度分别为95%、65%.讨论了各种反应条件对取代度的影响,并对修饰改性的聚苯醚进行了表征。
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| 关 键 词： | 聚苯醚 胺化 硝化 取代度 |
| 收稿时间： | 1995-11-22 |
| 修稿时间： | 1996-03-18 |
Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups |
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| Pan Yan, Huang Yuhui, Cong Guangmin.Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups[J].Chinese Journal of Applied Chemistry,1996,0(5):10-13. |
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| Authors: | Pan Yan Huang Yuhui Cong Guangmin |
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| Institution: | Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650 |
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| Abstract: | The chemical modification of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) has been carried out by incorporating nitro or amino groups in the PPO backbone. The obtained maximum monosubstitution value is 95% or 65% respectively. The effects of reaction conditions on the functional group contents in PPO were discussed. The modified PPO obtained was characterized by FT-IR、1H NMR spectroscopy, nitrogen analysis, solubility test and X-ray diffraction study. |
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| Keywords: | poly(phenylene oxide) amination nitration substitution value |
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