| 纳米TiO2光催化降解聚乙二醇反应 |
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| 引用本文： | 吴缨,范崇政,司靖宇.纳米TiO2光催化降解聚乙二醇反应[J].应用化学,2005,22(11):1253-0. |
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| 作者姓名： | 吴缨 范崇政 司靖宇 |
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| 作者单位： | a合肥学院化学与材料工程系；b中国科学技术大学化学物理系 |
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| 基金项目： | 合肥学院科学研究发展基金资助项目(05ky018zr) |
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| 摘 要： | 纳米TiO2光催化降解聚乙二醇反应;纳米二氧化钛; 光催化; 聚乙二醇
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| 关 键 词： | 纳米TiO2光催化降解聚乙二醇反应 纳米二氧化钛 光催化 聚乙二醇 |
| 文章编号： | 1000-0518(2005)11-1253-05 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2004年12月6日 |
Photocatalytic Degradation of Polyethylene Glycol with TiO2 Nanoparticles |
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| WU Ying,FAN Chong-Zheng,SI Jing-Yu.Photocatalytic Degradation of Polyethylene Glycol with TiO2 Nanoparticles[J].Chinese Journal of Applied Chemistry,2005,22(11):1253-0. |
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| Authors: | WU Ying FAN Chong-Zheng SI Jing-Yu |
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| Abstract: | The photocatalytic degradation of polyethylene glycol(PEG) with TiO_(2) nanoparticles as the photocatalyst was investigated.The fact that the amount of CO_(2) and the concentration of residue varied with reaction time indicates that it is a reaction of zero order and the degradation rate of PEG is negatively proportional to the average molecular weight of PEG.TGA and NMR results show that low molecular weight PEG,esters and(other) intermediates were produced during the degradation reaction.PEG was finally mineralized to CO_(2) and(H_2O). |
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| Keywords: | TiO_(2) nanoparticles photocatalysis polyethylene glycol |
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