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| 十八硫醇自组装膜对TiO2光电氧化甲醇的敏化作用 | |
| 引用本文： | 丁克强,贾振斌,王庆飞,曹江林,田娜,童汝亭,王心葵.十八硫醇自组装膜对TiO2光电氧化甲醇的敏化作用[J].应用化学,2002,19(1):91-0. |
| 作者姓名： | 丁克强 贾振斌 王庆飞 曹江林 田娜 童汝亭 王心葵 |
| 作者单位： | 1. 中国科学院山西煤炭化学研究所,太原;河北师范大学化学系,石家庄,050016 2. 河北师范大学化学系,石家庄,050016 3. 中国科学院山西煤炭化学研究所,太原 |
| 基金项目： | 河北省自然科学基金 ( 2 9815 9)，河北省博士生基金资助项目 |
| 摘 要： | 纳米电极;甲醇光电氧化;十八硫醇自组装膜对TiO2光电氧化甲醇的敏化作用 |
| 关 键 词： | 纳米电极 甲醇光电氧化 十八硫醇自组装膜对TiO2光电氧化甲醇的敏化作用 |
| 文章编号： | 1000-0518(2002)01-0091-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2001年4月23日 |
The Sensitization of Self-assembled Monolayer Formed by Octadecanethiol for TiO2 Nanoporous Film Electrode in CH3OH Photo-electro-oxidation |
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| DING Ke-Qiang a,b,JIA Zhen-Bin b,WANG Qing-Fei b,CAO Jiang-Lin b,TIAN Na b,TONG Ru-Ting b,WANG Xin-Kui a.The Sensitization of Self-assembled Monolayer Formed by Octadecanethiol for TiO2 Nanoporous Film Electrode in CH3OH Photo-electro-oxidation[J].Chinese Journal of Applied Chemistry,2002,19(1):91-0. | |
| Authors: | DING Ke-Qiang a b JIA Zhen-Bin b WANG Qing-Fei b CAO Jiang-Lin b TIAN Na b TONG Ru-Ting b WANG Xin-Kui a |
| Institution: | DING Ke-Qiang a,b*,JIA Zhen-Bin b,WANG Qing-Fei b,CAO Jiang-Lin b,TIAN Na b,TONG Ru-Ting b,WANG Xin-Kui a |
| Abstract: | The photocurrent created by the TiO 2 nanoporous film electrode modified by octadecanethiol(18SH) self-assembled monolayer(SAM) was found to be 1 95 times greater than that without modification as shown by cyclic voltammetry(CV). Meanwhile the maximum adsorbed peak has extended to the infrared range for about 20 nm. The formation of SAM was also assured with CV and small amplitude isosceles triangle potential methods, where the sensitization of SAM on the oxidation of CH 3OH on the TiO 2 nanoporous film electrode could be observed clearly. The results elucidated that the increased photocurrent by modification of octadecanethiol could not be simply attributed to the oxidation of octadecanethiol or ethanol. The results also implied that the application of SAM would be practicable in the sensitization of TiO 2 nanoporous film electrode in solar cell area. |
| Keywords: | alkanethiol self-assembled monolayer TiO 2 nanoporous film electrode methanol oxidation |
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