| 电喷雾质谱法和高效液相色谱法对dpq、ttd合成机理探讨 |
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| 引用本文： | 陶建清,孙冲,张利民,费正皓,顾志国.电喷雾质谱法和高效液相色谱法对dpq、ttd合成机理探讨[J].应用化学,2005,22(11):1234-0. |
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| 作者姓名： | 陶建清 孙冲 张利民 费正皓 顾志国 |
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| 作者单位： | a盐城师范学院化学系；b江苏省环境科学研究院重点实验室；c南京大学配位化学国家重点实验室 |
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| 基金项目： | 江苏省教育厅自然科学基金项目(No.02KJB150010)，江苏省环境科学研究院重点实验室开放基金项目(No.KF0407) |
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| 摘 要： | 电喷雾质谱法和高效液相色谱法对dpq、ttd合成机理探讨;电喷雾质谱;高效液相色谱;反应机理;配体dpq;配体ttd
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| 关 键 词： | 电喷雾质谱法和高效液相色谱法对dpq、ttd合成机理探讨 电喷雾质谱 高效液相色谱 反应机理 配体dpq 配体ttd |
| 文章编号： | 1000-0518(2005)11-1234-05 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2004年12月2日 |
Mechanism for Preparation of Condensed Rings Compounds Containing Nitrogen Analyzed with HPLC and ESI-MS |
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| TAO Jian-Qin,SUN Chong,ZHANG Li-Min,FEI Zheng-Hao,GU Zhi-Guo.Mechanism for Preparation of Condensed Rings Compounds Containing Nitrogen Analyzed with HPLC and ESI-MS[J].Chinese Journal of Applied Chemistry,2005,22(11):1234-0. |
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| Authors: | TAO Jian-Qin SUN Chong ZHANG Li-Min FEI Zheng-Hao GU Zhi-Guo |
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| Institution: | TAO Jian-Qin~ |
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| Abstract: | The interactions between phen-5,6-dione and ethyldiamine or cis-diaminomaleonitrile were studied via high performance liquid chromatography and electrospray ionization mass spectrometry respectively.The(results) show that the intermediate from the addition reaction between the carbonyl and amine groups formed first,it was further dehydrated to form the double bond.And if a conjugated system could be formed,the(resulting) intermediate would be dehydrogenated further into conjugated compounds of condensed rings. |
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| Keywords: | ESI-MS high performance liquid chromatography(HPLC) mechanism of reaction ligand dpq ligand ttd |
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