| 用于月桂酸胺化的Cu-Ni-Mg三元催化剂的研究 |
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| 引用本文： | 李秋小,张高勇,彭少逸.用于月桂酸胺化的Cu-Ni-Mg三元催化剂的研究[J].应用化学,2001,18(9):693-696. |
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| 作者姓名： | 李秋小 张高勇 彭少逸 |
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| 作者单位： | 中国日用化学工业研究所，中科院山西煤炭化学研究所，中国科学院山西煤炭化学研究所 |
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| 摘 要： | 催化胺化;用于月桂酸胺化的Cu-Ni-Mg三元催化剂的研究
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| 关 键 词： | 催化胺化 用于月桂酸胺化的Cu-Ni-Mg三元催化剂的研究 |
| 文章编号： | 1000-0518(2001)09-0693-04 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2000年10月18 |
The Cu-Ni-Mg Catalysts for Catalytic Amination of Dodecyl Alcohol |
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| LI Qiu Xiao ,ZHANG Gao Yong.The Cu-Ni-Mg Catalysts for Catalytic Amination of Dodecyl Alcohol[J].Chinese Journal of Applied Chemistry,2001,18(9):693-696. |
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| Authors: | LI Qiu Xiao ZHANG Gao Yong |
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| Institution: | LI Qiu Xiao *,ZHANG Gao Yong |
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| Abstract: | The effects of addition of Mg to CaCO 3 supported Cu Ni catalyst in catalytic amination of dodecyl alcohol with dimethylamine have been investigated. It is found that Mg can effectively promote the selectivity of the catalyst due to its prohibition effect on the reduction of Ni. The XPS results of the catalysts revealed that Ni in the catalyst with added Mg has a relatively higher positive charge. The higher the positive charge of Ni, the higher the selectivity of the catalysts. |
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| Keywords: | lauryl alcohol catalytic amination Cu Ni Mg catalysts |
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