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Ag/TiO2对含酚废水的光电催化降解
引用本文:刘守新,陈广胜,陈孝云,陈曦,孙承林.Ag/TiO2对含酚废水的光电催化降解[J].应用化学,2005,22(8):840-0.
作者姓名:刘守新  陈广胜  陈孝云  陈曦  孙承林
作者单位:1. 东北林业大学材料科学与工程学院,哈尔滨,150040;中国科学院大连化学物理研究所,大连,116023
2. 东北林业大学材料科学与工程学院,哈尔滨,150040
3. 中国科学院大连化学物理研究所,大连,116023
基金项目:国家自然科学基金(30400339),黑龙江省自然科学基金(C2004-29)资助项目
摘    要:Ag/TiO2对含酚废水的光电催化降解;Ag/TiO2; 光电催化; 苯酚;电解质

关 键 词:Ag/TiO2对含酚废水的光电催化降解  Ag/TiO2  光电催化  苯酚  电解质
文章编号:1000-0518(2005)08-0840-04
收稿时间:2009-06-29
修稿时间:2004年9月20日

Electro-Photocatalytic Degradation of Phenol in Wastewater Using Ag/TiO2 Photocatalysts
LIU Shou-xin,CHEN Guang-Sheng,CHEN Xiao-Yun,CHEN Xi,SUN Cheng-lin.Electro-Photocatalytic Degradation of Phenol in Wastewater Using Ag/TiO2 Photocatalysts[J].Chinese Journal of Applied Chemistry,2005,22(8):840-0.
Authors:LIU Shou-xin  CHEN Guang-Sheng  CHEN Xiao-Yun  CHEN Xi  SUN Cheng-lin
Institution:LIU Shou-Xin~
Abstract:In the present work, suspended Ag/TiO_2 was used as the catalyst, Ti mesh as the electrode, and a three-dimension electrode of Ti/Ag/TiO_(2) was constructed. The effect of enforced electric field was observed, and the electro-photocatalytic degradation of phenol in aqueous solution at the prepared electrode were (evaluated). The results show that the anode potential bias favors the photocatalytic degradation of (phenol). The maximum phenol removal efficiency was achieved when TiO_2 ith 1.5% silver loading was used. Two optimal voltage values for the Ag/TiO_(2) electro-photocatalysis reaction were 20 and 10 V, respectively. (Addition) of (electrolyte) NaCl increased the phenol removal efficiency of Ag/TiO_2 electro-photocatalysis from 49.7% to 93.6%. Enforced electric field can drive photogenerated electrons away from the photocatalyst (surface), and the enhanced photocatalytic activity is mainly caused by the low recombination rate of (electrons) and holes and the higher rate of electron transfer to adsorbed oxygen.
Keywords:Ag/TiO_2  electro-photocatalysis  phenol  electrolyte
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