| 轴向为烷氧基配位的萘酞菁硅配合物的光谱及光稳定性 |
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| 引用本文： | 牛晓宇,吴谊群,陈耐生,黄金陵.轴向为烷氧基配位的萘酞菁硅配合物的光谱及光稳定性[J].应用化学,2006,23(2):153-0. |
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| 作者姓名： | 牛晓宇 吴谊群 陈耐生 黄金陵 |
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| 作者单位： | a福州大学功能材料研究所；b黑龙江大学化学化工学院；c中国科学院上海光学精密机械研究所 |
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| 基金项目： | 中国科学院资助项目;国家自然科学基金 |
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| 摘 要： | 轴向为烷氧基配位的萘酞菁硅配合物的光谱及光稳定性;萘酞菁硅;轴向烷氧基配位;光谱性质;光稳定性
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| 关 键 词： | 轴向为烷氧基配位的萘酞菁硅配合物的光谱及光稳定性 萘酞菁硅 轴向烷氧基配位 光谱性质 光稳定性 |
| 文章编号： | 1000-0518(2006)02-0153-04 |
| 收稿时间： | 2005-04-16 |
| 修稿时间： | 2005-06-16 |
Spectra and Photostability of Axially Alkoxy Substituted Naphthalocyanine Silicon Coordination Compounds |
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| Niu Xiao-Yu,WU Yi-Qun,CHEN Nai-Sheng,HUANG Jin-Ling.Spectra and Photostability of Axially Alkoxy Substituted Naphthalocyanine Silicon Coordination Compounds[J].Chinese Journal of Applied Chemistry,2006,23(2):153-0. |
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| Authors: | Niu Xiao-Yu WU Yi-Qun CHEN Nai-Sheng HUANG Jin-Ling |
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| Institution: | 1.Institute of Functional Materials, Fuzhou University, Fuzhou 350002 ; 2. College of Chemistry and Chemical Engineering,Heilongjiang University, Harbin ; 3. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai |
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| Abstract: | The UV spectra,photo-degradation kinetics,and photostability of four axially alkoxy(substituted) naphthalocyanine silicon compounds(SiNc(OR)_(2),R=CH_(3),C_(2)H_(5),C_(3)H_(7) and C_(4)H_(9)) were investigated in DMSO,DMF and CH_(2)Cl_(2),respectively.The results indicate that the maximal absorption bands of the compounds increase with increased carbon number of the axially alkoxy substituted groups in the same solvent.Moreover,the photostability also gradually increase with increased carbon number of the axially alkoxy substituted groups in DMSO and CH_(2)Cl_(2).The photostability order for the same SiNc(OR)_(2) compound in(different) solvent is:DMSO>CH_(2)Cl_(2)>DMF. |
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| Keywords: | naphthalocyanine silicon axially alkoxy substitution spectra and photostability |
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