| 椰壳炭磺酸催化剂制备及其对杯[4]芳烃合成反应的催化应用 |
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| 引用本文： | 左传鹏,阳志高,尹笃林,袁治冶,徐琼,毛丽秋.椰壳炭磺酸催化剂制备及其对杯[4]芳烃合成反应的催化应用[J].应用化学,2010,27(2):237-239. |
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| 作者姓名： | 左传鹏 阳志高 尹笃林 袁治冶 徐琼 毛丽秋 |
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| 作者单位： | 化学生物学及中药分析教育部重点实验室,湖南师范大学精细催化合成研究所,长沙,410081 |
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| 摘 要： | 以废弃椰壳为原料,经炭化和磺化制得新型固体磺酸催化剂,用于催化各种芳醛与间苯二酚的缩合反应,以较高收率(49%～95%)制得一系列杯4]芳烃化合物,产物结构经IR、1H NMR和MS测试技术表征得以确证。
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| 关 键 词： | 椰壳炭磺化 固相催化 研磨反应 取代苯甲醛 间苯二酚 |
| 收稿时间： | 2009-03-20 |
| 修稿时间： | 2009-06-28 |
Preparation of Coconut Char Sulfonic Acid and Its Catalytical Application for Synthesis of Calix[4] resorcinarenes |
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| ZUO Chuan-Peng,YANG Zhi-Gao,YIN Du-Lin,YUAN Zhi-Ye,XU Qiong,MAO Li-Qiu.Preparation of Coconut Char Sulfonic Acid and Its Catalytical Application for Synthesis of Calix[4] resorcinarenes[J].Chinese Journal of Applied Chemistry,2010,27(2):237-239. |
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| Authors: | ZUO Chuan-Peng YANG Zhi-Gao YIN Du-Lin YUAN Zhi-Ye XU Qiong MAO Li-Qiu |
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| Institution: | ZUO Chuan-Peng,YANG Zhi-Gao,YIN Du-Lin,YUAN Zhi-Ye,XU Qiong,MAO Li-Qiu(Key Laboratory of Chemical Biology , Traditional Chinese Medicine Research,Ministry of Education,Institute of Fine Catalysis , Synthesis,Hunan Normal University,Changsha 410081) |
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| Abstract: | A novel solid sulfonic acid was prepared from coconut shell via carbonization and sulfonation and used as a catalyst for the condensation of aldehydes and resorcinol,and calix4]resorcinarenes were prepared rapidly in good yield(49%~95%). The structures of the target compounds were confirmed by IR,1H NMR and MS. |
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| Keywords: | coconut char solid-state catalyst grinding method aldehyde resorcinol calix[4]resorcinarenes |
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