A chiral cyclohexanone linked to polystyrene for solid-phase synthesis of chiral alpha-carbonyls |
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| Authors: | Spino Claude Gund Vitthal Genbhau Nadeau Christian |
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| Institution: | Département of Chimie, Université of Sherbrooke, 2500 Boulevard Université, Sherbrooke, Qc, Canada, J1K 2R1. Claude.Spino@USherbrooke.ca |
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| Abstract: | Two chiral cyclohexanones were linked to polystyrene resin. The polymer-bound auxiliaries were subjected to a sequence of four reactions, the last of which cleaves the desired alpha-chiral carbonyl compound off the resin, concurrently regenerating the resin-bound auxiliary in its original form. The resin can then be reused. |
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