| THE STUDY OF SPECTRA AND X-RAY CRYSTAL STRUCTURE OF A NOVEL BIONICS INSECTICIDE——(CH_3)_2NHCH(CH_2S_2O_3)_2Na·H_2O |
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| 引用本文： | 张泽莹,唐有祺,段成钢,唐庄.THE STUDY OF SPECTRA AND X-RAY CRYSTAL STRUCTURE OF A NOVEL BIONICS INSECTICIDE——(CH_3)_2NHCH(CH_2S_2O_3)_2Na·H_2O[J].中国科学B辑(英文版),1985(11). |
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| 作者姓名： | 张泽莹 唐有祺 段成钢 唐庄 |
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| 作者单位： | Institute of Physical Chemistry，Peking University，Institute of Physical Chemistry，Peking University，Institute of Chemical Industry of Guizhou Province，Guiyang，Institute of Chemical Industry of Guizhou Province，Guiyang |
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| 摘 要： | IR and NMR spectra of novel bionics insecticide—C_5NS_4O_6H_(12)Na·H_2O have been studied. The molecular and crystal structures of the compound also have been determined. The compound crystallizes in the monoclinic space group C_(2h)~5, - P2_1/n with α= 8.0972. (9) , b =16.262(4), c = 10.370(3), β= 94.26(2)° and z = 4.The result shows that N atom in this compound captures a proton to form HN~ group, Na~ is in statistical disorder. Therefore, the structural formula of tho compound is (CH_3)_2HN~ —CH(CH_2S_2O_3~-)_2·1/2 (Na~ )_2·H_2O.
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