| STUDY ON ESR SPECTRUM OF BIS(2-HYDROXYL-PHENYLKETOXIME)-COPPER (Ⅱ) COMPLEX |
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| 引用本文： | 徐元植,陈德余,李晓平,周澄明,陈星,袁承业.STUDY ON ESR SPECTRUM OF BIS(2-HYDROXYL-PHENYLKETOXIME)-COPPER (Ⅱ) COMPLEX[J].中国科学B辑(英文版),1988(1). |
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| 作者姓名： | 徐元植 陈德余 李晓平 周澄明 陈星 袁承业 |
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| 作者单位： | Department of Chemistry，Zhejiang University，Hangzhou，Department of Chemistry，Zhejiang University，Hangzhou，Fujian Instiute of Structure of Matter，Academia sinica，Fuzhou.，Shanghai Institute of Organic Chemistry，Academia Sinica，Shanghai Institute of Organic Chemistry，Academia Sinica，Shanghai Institute of Organic Chemistry，Academia Sinica |
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| 摘 要： | A better resolution of ESR spectrum of bis(2-hydroxyl-phenylketoxime)copper (Ⅱ) complex intetrahydrofuran (THF) solution, measured at liquid nitrogen temperature, was analyzed. From thespectrum, we have not only got hyperfine splitting of the ~(63)Cu and ~(65)Cu, but also very nice super-hyperfine splitting arising from ~(14)N nucleus. The g_x, g_y, g_z; A_x~(63), A_y~(63), A_z~(63); A_x~(65), A_y~(65), A_z~(65); A_∥~N andA_⊥~N etc. tensor parameters were determined rather reasonably. From these, we calculated the bondingparameters of this complex, and discussed its electronic structure.
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