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氮掺杂TiO2纳米管阵列的制备及其可见光光电催化活性研究
引用本文:庄惠芳,赖跃坤,李静,孙岚,林昌健.氮掺杂TiO2纳米管阵列的制备及其可见光光电催化活性研究[J].电化学,2007,13(3):284-287.
作者姓名:庄惠芳  赖跃坤  李静  孙岚  林昌健
作者单位:固体表面物理化学国家重点实验室,厦门大学化学系,福建,厦门,361005
基金项目:国家自然科学基金,福建省纳米专项项目(50571085,2005HZ01-3)资助
摘    要:联用电化学阳极氧化和湿化学法制备氮掺杂的TiO2纳米管阵列膜.应用SEM、XPS、DRS分析、表征,并研究该膜层的形貌、组成和光学性质以及在卤钨灯照射下降解甲基橙水溶液的光电催化活性.结果表明:氮以取代掺杂的形式进入TiO2晶格,掺氮的TiO2纳米管阵列在可见光区有较强的吸收,其光电催化性能优于纯的TiO2纳米管阵列膜.

关 键 词:二氧化钛  纳米管阵列  氮掺杂  可见光活性
文章编号:1006-3471(2007)03-0284-04
收稿时间:2007-04-19
修稿时间:2007-05-07

Fabrication and Charaterization of Nitrogen-Doped TiO2 Nanotube Array and Its Visible Light Activity
ZHUANG Hui-fang,LAI Yue-kun,LI Jing,SUN Lan,LIN Chang-jian.Fabrication and Charaterization of Nitrogen-Doped TiO2 Nanotube Array and Its Visible Light Activity[J].Electrochemistry,2007,13(3):284-287.
Authors:ZHUANG Hui-fang  LAI Yue-kun  LI Jing  SUN Lan  LIN Chang-jian
Institution:State Key Laboratory of Physical Chemistry of Solid Suofuces, Department of Chemistry, Xiamen University, Xiamen 361005, Fujian, China
Abstract:Nitrogen-doped TiO2 nanotube array was fabricated by an electrochemical anodic oxidation followed a wet process.XPS result indicates that the nitrogen atoms were doped into lattice of TiO2 nanotubes.The UV-Vis spectra show that the photoabsorption of N-doped TiO2 nanotube array film is enhanced in the visible light region.Compared with the TiO2 nanotube array film,the N-doped TiO2 nanotubes exhibite a higher photocatalytic activity which is evaluated by the decomposition rate of methyl orange using the tungsten-halogen lamp as light source.
Keywords:titanium oxide  nanotube array  n-doped  visible light activity
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