| 纯铝在KOH-乙醇溶液中的电化学行为 |
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| 引用本文： | 邵海波,王建明,王晓艳,郑奕,张鉴清.纯铝在KOH-乙醇溶液中的电化学行为[J].电化学,2004,10(4):430-434. |
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| 作者姓名： | 邵海波 王建明 王晓艳 郑奕 张鉴清 |
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| 作者单位： | 浙江大学化学系,浙江大学化学系,浙江大学化学系,浙江大学化学系,浙江大学化学系 浙江杭州310027
,浙江杭州310027
,浙江杭州310027
,浙江杭州310027
,浙江杭州310027 |
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| 基金项目： | 国家重大基础规划 (G1 9990 6 50 )项目资助 |
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| 摘 要： | 研究纯铝在KOH 乙醇溶液中的电化学行为,腐蚀失重、极化曲线、EIS和恒电流放电实验表明,该体系纯铝的腐蚀速率极小,因而有可能应用于密闭电池,并可在相当宽的电位范围内保持一定的活性.放电的终止可能是由于放电产物在电极表面堆积引起的.
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| 关 键 词： | 纯铝 KOH乙醇溶液 电化学行为 |
| 文章编号： | 1006-3471(2004)04-0430-05 |
| 收稿时间： | 2004-11-28 |
| 修稿时间： | 2004年1月4日 |
Anodic Dissolution of Aluminum in KOH-Ethanol Solutions |
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| SHAO Hai-bo,WANG Jian-ming,WANG Xiao-yan,ZHENG Yi,ZHANG Jian-qing.Anodic Dissolution of Aluminum in KOH-Ethanol Solutions[J].Electrochemistry,2004,10(4):430-434. |
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| Authors: | SHAO Hai-bo WANG Jian-ming WANG Xiao-yan ZHENG Yi ZHANG Jian-qing |
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| Institution: | SHAO Hai-bo,WANG Jian-ming~*,WANG Xiao-yan,ZHENG Yi,ZHANG Jian-qing |
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| Abstract: | The feasibility of employing aluminum in KOH ethanol solution as a battery anode system was discussed. Weight loss measurement showed that the corrosion rate of Al is low enough to be used in sealed batteries. Through the measurements done by anodic polarization, EIS and galvanostatic discharge, it was found that A1 is electrochemical active in a wide potential range in this system, and its discharge mechanism is similar to that of A1 in aqueous solution. The discharge potential increased rapidly after a period of time, which might be caused by the discharge products depositing on the electrode surface. |
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| Keywords: | Pure aluminum KOH ethanol solution Electrochemical behavior |
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