| 聚溴酚蓝修饰玻碳电极的制备及电化学性质 |
| |
| 引用本文： | 陈伟,罗红斌,林新华.聚溴酚蓝修饰玻碳电极的制备及电化学性质[J].电化学,2005,11(1):92-95. |
| |
| 作者姓名： | 陈伟 罗红斌 林新华 |
| |
| 作者单位： | 福建医科大学药学院,福建,福州,350004 |
| |
| 摘 要： | 在含溴酚蓝的磷酸缓冲溶液中，应用循环伏安法于经预处理的玻碳电极上形成聚合物薄膜，结果表明，在-1．0V～ 1．8V(vs．Ag／AgCl)扫描电位之间形成的薄膜具有较高的电活性和稳定性，该电极对抗坏血酸电化学氧化有催化作用，既使抗坏血酸的氧化电位负移了270mV，又增大了其氧化峰电流，催化峰电流与抗坏血酸浓度在2．5～250μg/mL范围内呈良好的线性关系。
|
| 关 键 词： | 溴酚蓝 电化学聚合 电催化氧化 抗坏血酸 玻碳电极 |
| 文章编号： | 1006-3471(2005)01-0092-04 |
| 修稿时间： | 2004年5月17日 |
Preparation of Poly ( Bromophenol Blue ) Modified Glassy Carbon Electrode and its Electrocatalytic Activity |
| |
| CHEN Wei,LUO Hong-bin,LIN Xin-hua.Preparation of Poly ( Bromophenol Blue ) Modified Glassy Carbon Electrode and its Electrocatalytic Activity[J].Electrochemistry,2005,11(1):92-95. |
| |
| Authors: | CHEN Wei LUO Hong-bin LIN Xin-hua |
| |
| Abstract: | A film of poly ( bromophenol blue ) was formed on a glassy carbon electrode by using cyclic voltammetry. A stable film could be obtained with a potential range from -1.0V to +1.8V(vs.Ag/AgCl). The experimental results showed that the poly ( bromophenol blue ) modified glassy carbon electrode could catalyse the oxidation of ascorbic acid. It decreased the oxidation potential by about 270mV but increased the peak current. Meanwhile, this electrode showed a good linear current response for the ascorbic acid range from 2.5 to 250 (g/mL.) |
| |
| Keywords: | Bromophenol blue Electrochemically polymerization Electrocatalytic oxidation Ascorbic acid Glassy carbon electrode |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
