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软化学技术合成高容量锂二次电池正极材料AgV_3O_8(英文)
引用本文:曹晓雨,李涛,谢玲玲,闫向阳,王驰伟.软化学技术合成高容量锂二次电池正极材料AgV_3O_8(英文)[J].电化学,2008,14(2).
作者姓名:曹晓雨  李涛  谢玲玲  闫向阳  王驰伟
作者单位:1. 河南工业大学化学化工学院,河南,郑州,450001
2. 深圳比克电池有限公司,广东,深圳,518119
基金项目:河南工业大学校科研和教改项目
摘    要:应用软化学方法合成层状AgV3O8正极材料,并用XRD(粉末X-射线衍射)、SEM(扫描电子显微镜)和LPSA(激光粒度分析)表征了材料的结构和形貌,采用恒流充放电技术研究了其电化学性能.SEM和LPSA测试结果显示所制备的材料具有较小的颗粒尺寸和较窄的粒度分布区间.恒流充放电测试结果表明,该材料具有高的放电比容量,其中400 ℃下获得的材料首次放电容量高达760.5 mAh/g.

关 键 词:软化学合成  AgV3O8  正极材料  锂二次电池  soft  chemistry  synthesis  AgV3O8  cathode  material  lithium  secondary  batteries  软化学技术  合成  高容量  电池正极材料  Technique  Chemistry  Soft  Batteries  Secondary  Lithium  Cathode  Materials  cathode  material  synthesized  high  discharge  capacity  results  sizes  small  distribution  narrow

Synthesis of AgV_3O_8 as High-Capacity of Cathode Materials for Lithium Secondary Batteries via a Soft Chemistry Technique
CAO Xiao-yu,LI Tao,XIE Ling-ling,YAN Xiang-yang,WANG Chi-wei.Synthesis of AgV_3O_8 as High-Capacity of Cathode Materials for Lithium Secondary Batteries via a Soft Chemistry Technique[J].Electrochemistry,2008,14(2).
Authors:CAO Xiao-yu  LI Tao  XIE Ling-ling  YAN Xiang-yang  WANG Chi-wei
Institution:CAO Xiao-yu1,LI Tao1,XIE Ling-ling1,YAN Xiang-yang1,WANG Chi-wei2(1.School of Chemistry , Chemical Engineering,Henan University of Technology,Zhengzhou 450001,China,2.Shenzhen Bak Battery Co.,LTD,Shenzhen 518119,Guangdong,China)
Abstract:The layered cathode material of AgV3O8 has been prepared for the lithium secondary batteries via the soft chemistry technique. The so-synthesized powders were characterized by XRD(powder X-ray diffraction),SEM(scanning electron microscope) and LPSA(laser particle size analysis).The electrochemical property was investigated by the galvanostatic discharge-charge technique.The results indicated that the particale sizes of AgV3O8 prepared were small in the distribution of narrow range,which leads to high discha...
Keywords:soft chemistry synthesis  AgV3O8  cathode material  lithium secondary batteries  
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