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新型锂电池用复合隔膜的制备及其电化学性能表征
引用本文:程琥,杜洪彦,杨勇.新型锂电池用复合隔膜的制备及其电化学性能表征[J].电化学,2004,10(3):303-306.
作者姓名:程琥  杜洪彦  杨勇
作者单位:厦门大学化学系,固体表面物理化学国家重点实验室,福建,厦门,361005;厦门大学化学系,固体表面物理化学国家重点实验室,福建,厦门,361005;厦门大学化学系,固体表面物理化学国家重点实验室,福建,厦门,361005
基金项目:国家自然科学基金(29925310,20021002),霍英东优秀青年教师基金资助
摘    要:利用浸渍法在聚丙烯微孔膜(Celgard 2400)表面涂覆掺有纳米二氧化硅的聚氧乙烯(PEO),制备了新型锂电池用复合隔膜.采用交流阻抗法、扣式电池充放电等实验技术测试了复合隔膜的电化学性能.

关 键 词:锂离子电池  隔膜  二氧化硅  聚氧化乙烯
文章编号:1006-3471(2004)03-0303-04
修稿时间:2003年12月12

Preparation and Electrochemical Performance of New Composite Seperators for Lithium-ion Batteries
CHENG Hu,DU Hong-yan,YANG Yong.Preparation and Electrochemical Performance of New Composite Seperators for Lithium-ion Batteries[J].Electrochemistry,2004,10(3):303-306.
Authors:CHENG Hu  DU Hong-yan  YANG Yong
Institution:CHENG Hu,DU Hong-yan,YANG Yong~
Abstract:New composite seperators for lithium ion batteries were prepared by coating PEO mixed with nanosize SiO_(2)onto microporous polypropylene(PP) seperators. Highly conductive electrolytes were prepared by soaking them in an electrolyte solution. With these composite separators, the lithium ion cell consisting of Li anode and LiNi_(0.8)Co_(0.2)O_(2)cathode were assembled. The high initial discharge capacity and good capacity retention were obtained through the cell.
Keywords:Lithium ion batteries  Separators  Silicon dioxide  Poly(ethylene oxide)
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